Air quality in Europe continues to remain poor in many areas, with regulation limits often exceeded by many countries. The EU Life-IP PREPAIR Project, involving administrations and environmental protection agencies of eight regions and three municipalities in Northern Italy and Slovenia, was designed to support the implementation of the regional air quality plans in the Po Valley, one of the most critical areas in Europe in terms of pollution levels. In this study, four air quality modelling systems, based on three chemical transport models (CHIMERE, FARM and CAMx) were applied over the Po Valley to assess the sensitivity of PM_2.5 concentrations to NO_x and NH₃ emission reductions. These two precursors were reduced (individually and simultaneously) from 25% up to 75% for a total of 10 scenarios, aimed at identifying the most efficient emission reduction strategies and to assess the non-linear response of PM_2.5 concentrations to precursor changes. The multi-model analysis shows that reductions across multiple emission sectors are necessary to achieve optimal results. In addition, the analysis of non-linearities revealed that during the cold season, the efficiency of PM_2.5 abatement tends to increase by increasing the emission reductions, while during summertime, the same efficiency remains almost constant, or slightly decreases towards higher reduction strengths. Since the concentrations of PM_2.5 are greater in winter than in summer, it is reasonable to infer that significant emission reductions should be planned to maximise reduction effectiveness.

Assessing secondary and primary NO₂ in urban areas is important to support carefully designed environmental policies, particularly in areas with recurrent exceedance of NO₂ regulatory limits. The share of secondary NO₂ was preliminary estimated in intense traffic areas of Modena and Reggio Emilia (Northern Italy) by the combined analysis of regulatory air quality observations at urban traffic and urban background conditions. In addition simulations performed by the Lagrangian particle dispersion models Micro SWIFT SPRAY and the chemical transport model WRF-Chem were performed. The former was applied on the urban area representative of traffic conditions for both cities, in winter. The latter was applied twice in Modena, both with and without urban traffic emissions. Results suggest a large amount of secondary NO₂ mainly at the Modena traffic site, and a better representativity of background conditions of the corresponding urban station in Reggio Emilia. NO_x levels simulated by WRF-Chem show good results at Modena urban background and performance in line with reference benchmark values in reproducing observed NO₂ and NO_x concentrations at rural background sites, although a non-negligible bias in simulated urban NO₂ remained. Overall the simulation models suggest that contribution to atmospheric NO_x by domestic heating or industrial combustion emissions are not as relevant compared to traffic, consistently with the local emission inventory.

Light-absorbing aerosols (LAAs) are short-lived climate forcers with a significant impact on Earth's radiative balance. LAAs include dust aerosols, black carbon (BC) and organic light-absorbing carbonaceous aerosol (collectively termed brown carbon, BrC), which have also been proven to be highly toxic. In this study, aerosol absorption at five wavelengths (ranging from ultraviolet to infrared) was monitored continuously using filter-based photometers during two winter seasons in 2020 and 2021 in the city of Modena (southern central Po Valley, northern Italy), at two regulatory air quality monitoring sites, along with other pollutants (coarse particulate matter, PM₁₀; fine particulate matter, PM_2.5; O₃; NO; NO₂; and C₆H₆) and the vehicular traffic rate. The aerosol optical depth (AOD) and other column aerosol optical properties were concurrently monitored at four wavelengths by an AErosol RObotic NETwork (AERONET) sun photometer under urban background conditions within Modena. In situ absorption levels were apportioned to both sources (fossil fuel and biomass burning) and species (BC and BrC), while columnar absorption was apportioned to BC, BrC and mineral dust. The combined analysis of the atmospheric aerosol and gas measurements and of the meteorological conditions (in situ and from the ERA5 reanalysis) identified the location of potential urban sources of BC and BrC, most likely related to traffic and biomass burning. In situ data show different diurnal/weekly patterns for BrC from biomass burning and BC from traffic, with minor differences between the background and the urban traffic conditions. AERONET version 3 absorption aerosol optical depth (AAOD) retrievals at four wavelengths allowed the estimation of the absorptive direct radiative effect due to LAAs over the same period under the reasonable assumption that the AOD signal is concentrated within the mixing layer. AERONET retrievals showed a modest correlation of columnar absorption with planetary boundary layer (PBL)-scaled in situ observations, although the correlation improved significantly during a desert dust transport event that affected both in situ aerosol and columnar absorption, particularly in the blue spectrum range. A low correlation occurred between the contribution of BrC to aerosol absorption for the in situ and the columnar observations, with the BrC contribution being generally larger for in situ observations. Finally, evidence of a highly layered atmosphere during the study period, featuring significant spatial mixing and modest vertical mixing, was shown by ERA5-based atmospheric temperature profiles and by the large correlation of concurrent AERONET AOD retrievals in Modena and in Ispra (on the northwestern side of the Po Valley, ca. 225 km from Modena).

The development of a natural gas-fired tri-generation power plant (520 MW Combined Cycle Gas Turbines + 58 MW Tri-generation) in the Republic of San Marino, a small independent country in Northern Italy, is under assessment. This work investigates the impact of atmospheric emissions of NO_x by the plant, under the Italian and European regulatory framework. The impact assessment was performed by the means of the Aria Industry package, including the 3D Lagrangian stochastic particle dispersion model SPRAY, the diagnostic meteorological model SWIFT, and the turbulence model SURFPRO (Aria Technologies, France, and Arianet, Italy). The Republic of San Marino is almost completely mountainous, 10 km west of the Adriatic Sea and affected by land-sea breeze circulation. SPRAY is suitable for simulations under non-homogenous and non-stationary conditions, over a complex topography. The emission scenario included both a worst-case meteorological condition and three 10-day periods representative of typical atmospheric conditions for 2014. The simulated NO_x concentrations were compared with the regulatory air quality limits. Notwithstanding the high emission rate, the simulation showed a spatially confined environmental impact, with only a single NO_x peak at ground where the plume hits the hillside of the Mount Titano (749 m a.s.l.), 5 km west of the future power plant.