The presence of pharmaceuticals in the aquatic environment presents a challenge to modern science. The most significant impact this can induce is the emergence of antibiotic resistance, which can lead to a global health emergency. It is important to note that the impact of pharmaceuticals in the aquatic environment is not limited to antibiotic resistance. Pharmaceuticals can also affect the behaviour and reproductive systems of aquatic organisms, with cascading effects on entire ecosystems. Numerous studies have reported the emergence of pharmaceuticals due to the uncontrolled disposal of polluted domestic, agricultural, and industrial wastewater in water bodies. This work discusses the potential of pharmaceuticals that on one hand are highly important for mankind, yet their non-judicious usage and disposal induce equally intriguing and problematic conditions to the health of aquatic systems. Pathways through which pharmaceutics can make their way into water bodies are discussed. Furthermore, the risk imposed by pharmaceuticals on aquatic life is also elaborated. The possible and pragmatic remediation methods through which pharmaceutical products can be treated are also discussed. Emphasis is placed on the potential of phytoremediation and advanced oxidative process, and the factors affecting the efficacy of these remediation methods are discussed.

Heavy metals (HMs) are indestructible and non-biodegradable. Phytoremediation presents an opportunity to transfer HMs from environmental matrices into plants, making it easy to translocate from one place to another. The ornate features of HMs' phytoremediation are biophilia and carbon neutrality, compared to the physical and chemical remediation methods. Some recent studies related to LCA also support that phytoremediation is technically more sustainable than competing technologies. However, one major post-application challenge associated with HMs phytoremediation is properly managing HMs contaminated biomass generated. Such a yield presents the problem of reintroducing HMs into the environment due to natural decomposition and release of plant sap from the harvested biomass. The transportation of high yields can also make phytoremediation economically inviable. This review presents the design of a sustainable phytoremediation strategy using an ever-evolving life cycle assessment tool. This review also discusses possible post-phytoremediation biomass management strategies for the HMs contaminated biomass management. These strategies include composting, leachate compaction, gasification, pyrolysis, torrefaction, and metal recovery. Further, the commercial outlook for properly utilizing HMs contaminated biomass was presented.

In the present work, the operational conditions for improving the degradation rates of Total Petroleum Hydrocarbons (TPHs) in contaminated soil from a machinery park were optimized at a microcosms scale along a 90-days incubation period. In this study, bioremediation strategies and an organic amendment have been tested to verify the remediation of soil contaminated with different hydrocarbons, mineral oils, and heavy metals. Specifically, designed biostimulation and bioaugmentation strategies were compared with and without adding vermicompost. The polluted soil harboring multiple contaminants, partially attenuated for years, was used. The initial profile showed enrichment in heavy linear alkanes, suggesting a previous moderate weathering. The application of vermicompost increased five and two times the amounts of available phosphorus (P) and exchangeable potassium (K), respectively, as a direct consequence of the organic amendment addition. The microbial activity increased due to soil acidification, which influenced the solubility of P and other micronutrients. It also impacted the predominance and variability of the different microbial groups and the incubation, as reflected by phospholipid fatty acid (PLFA) results. An increase in the alkaline phosphatases and proteases linked to bacterial growth was displayed. This stimulation of microbial metabolism correlated with the degradation rates since TPHs degradation' efficiency after vermicompost addition reached 32.5% and 34.4% of the initial hydrocarbon levels for biostimulation and bioaugmentation, respectively. Although Polycyclic Aromatic Hydrocarbons (PAHs) were less abundant in this soil, results also decreased, especially for the most abundant, the phenanthrene. Despite improving the degradation rates, results revealed that recalcitrant and hydrophobic petroleum compounds remained unchanged, indicating that mobility, linked to bioavailability, probably represents the limiting step for further soil recovery.

42 Pags., 9 Tabls., 5 Figs. The definitive version is available at: http://www.sciencedirect.com/science/journal/03783774One of the main constraints of irrigated agriculture is off-siteNpollution due to export of nitrate in irrigation return flows (IRF). Models capable of simulating the growth of crops and the N loads in IRF as affected by irrigation and N fertilization may be valuable tools in watershed studies. The Agricultural Policy Environmental eXtender (APEX) model was used to assess bestmanagement practices for reducing off-siteN loads in the IRF of three Mediterranean irrigated watersheds (Akarsu in Turkey, La Violada in Spain and Sidi Rached in Algeria). The watersheds (ranging from 4013 to 10,971 ha) were monitored along three hydrological years to determine the volume of IRF and the NO3-N concentrations and loads in IRF. APEX was calibrated with the data of the first two years and validated with the last year's data. APEX adequately simulated crop evapotranspiration and the volume of IRF and N loads in the IRF (errors < 20%). Simulated annual values were in general more accurate than simulated monthly values. APEX predicted that improving irrigationmanagement (change of irrigation system and/or scheduling) will decrease N loads in IRF over current values by 45% (Akarsu), 40% (La Violada), and 8% (Sidi Rached). However, improved N fertilization only will reduce N loads in IRF by 17% (Akarsu) or below 5% (La Violada and Sidi Rached). Improving irrigationmanagement will increase IRF NO3-N concentrations by 19% in La Violada and will decrease or will remain the same in the other two watersheds. APEXsimulations identified the main soils (shallow and low water holding capacity soils) and crops (heavily fertilized or shallow-root crops) N polluters within the studied watersheds. Overall, APEX simulated that the improvement of irrigation performance was the bestmanagementstrategy to decrease off-siteNpollution while maintaining or increasing crop yields in the three studied Mediterranean watersheds.This study was supported by the European Commission research project (INCO-CT-2005-015031).Peer reviewe

Organic and inorganic contaminants are entrained into environmental systems through natural and anthropogenic processes, such as mining activities, manufacturing, and waste disposal. In terrestrial and aquatic environments, the contaminant(s) remediation can be achieved by immobilization, thereby inhibiting their dispersal and bioavailability. Mobilization, through leaching and plant uptake, is another process of pollutant removal. Phytoremediation has attracted attention as an eco-friendly alternative for the remediation of contaminated environments. However, the safe management of post-phytoremediation contaminated biomass poses many practical challenges. Understanding the fate of the pollutants in the plants allows the estimation of the possible transfer of the contaminants to the food chain ascertain by-products or residues during biofuel production. Metal-enriched fractions could be used as a valuable source of novel catalysts or reusable materials. The safe conversion of biomass into energy may require sequestering contaminants at any step of the process, preferably upstream of the energy conversion or as a pre-treatment of plant biomass. Through gasification or pyrolysis of post-remediation biomass, bioenergy products (including syngas, oil, hydrogen gas, biochar, and hydrochar) can be used for heating and electricity generation. A comparative evaluation among pyrolysis, gasification, combustion, and liquefaction/fermentation processes for biofuel production from post-phytoremediation biomass suggests that pyrolysis is the strategy with the lowest transfer of toxic metals to the final products. This review presents critical discussions of the processes involved in phytoremediation of contaminated environments, the redistribution of contaminants within plant biomass, the sustainable management of post-phytoremediation biomass, and the unintended environmental consequences of phytoremediation.

30 Pags., 3 Tabls., 9 Figs. The definitive version is available at: http://www.sciencedirect.com/science/journal/01678809Irrigation district salt balances identify the main sources and sinks of salts and quantify salt loads in irrigation return flows. Salt balances were performed in La Violada Irrigation District during the 80s (1982–1984), 90s (1995–1998) and 00s (2006–2008) decades. Total Dissolved Solids (TDS) and loads in irrigation return flows were related with changes in irrigation performance and infrastructures during these decades. TDS increased linearly to increases in Irrigation Consumptive Use Coefficient (ICUC) (P < 0.01), and decreased with increases in Drainage Fraction (DRF) (P < 0.001). The salt balances revealed that 82% of the exported salts originated from soil gypsum dissolution. Annual salt yields in return flows were high and similar in the 80s and 90s (about 19.3 Mg/ha year), and halved in the 00s (9.9 Mg/ha year) due to comparable reductions in irrigation and drainage volumes derived from a better irrigation performance. Irrigation season salt yields were high and steady around 14.1 Mg/ha for ICUC < 51% and DRF > 66%, and decreased exponentially for values above and below these thresholds, respectively. Therefore, the key management strategy to reduce salt discharge to downstream areas is to decrease drainage volumes by improving irrigation management.This work was sponsored by the Spanish Ministry of Science and Education project AGL2006-11860/AGR, the European Regional Development Fund (FEDER) and the European Union project INCO CT-2005-015031.Peer reviewe