The present work investigates the production of sodium bicarbonate in combination with the co-utilization of saline brine and carbon capture, utilization, and sequestration (CCUS). The use of ammonia in the traditional Solvay process could be eliminated by using a modified Solvay process. This study compared the modification with the addition of three buffering additives: Ca(OH)2, KOH, and NH4HCO3. The effectiveness of these processes, using two qualities of saline brine (desalination and aquifer), is compared based on the purity of the produced NaHCO3. It was found that the use of Ca(OH)2 did not produce high-purity NaHCO3, while NH4HCO3 and KOH performed better. Desalination brine utilization with NH4HCO3 resulted in the production of high-purity NaHCO3, while the second most suitable method involved the use of KOH, and the main co-product formed was Na2CO3. Geochemical modeling is performed in order to have insights into the carbonation (in the reactor) and precipitation (in the oven) behavior of the reactions. It predicted the precipitation of mineral phases well, though kinetics might hinder some saturated solids to dissolve first. The present study shows that accurate characterization is critical to accurately assess the success of modified Solvay processes. The use of QXRD and SEM analyses, complemented with geochemical modeling, helped to better understand the processes and the formation of NaHCO3. Further investigations on diverse brines could provide for their better utilization by the geological carbon sequestration and water desalination industries that produce them.
Residual stresses on welded joints have been studied by several methods. In this present work, residual stresses was measured by a novel methodology under development named Displacement of Coordinated Points (DCP). To evaluate anisotropy effects in steel plates, two directions of the weld bead were considered: Welding was performed in both parallel and transversal direction of rolled steel plate ASTM A131 grade AH36.The experiments showed higher values of the residual stress in the transversal direction of the lamination when compared with the longitudinal direction, evidencing the anisotropy effect of the material. It was also observed that the increasing in heat input induces higher residual stress.
Choosing welding parameters is an important step in welding process, directly influencing in the heat input provided to welded joints. This heat input value, along with temperature distribution in welded joints, provides, to the drafter, conditions of predicting the Heat Affected Zone (HAZ) extension, the kind of microstructure to be formed, and therefore, the effects of residual stress. Three welding parameters were switched, providing different welding conditions. Each condition was analyzed by SmartWeld 2011 software and macrography to find and compare the extension of HAZ. As for the residual stresses, calculated through Displacement of Coordinated Points (DCP) method. It is possible to choose the best parameters for the welded joint by GMAW process considering the parameters in study.
This research presents a point‐of‐use (POU) water treatment technology utilizing metal/metallic surfaces based on Triply Periodic Minimal Surface (TPMS) structured filtration infills. Computational Fluid Dynamics modeling using Ansys CFX software is employed to analyze the behavior of Escherichia coli bacteria within a continuous liquid phase moving through the filtration infill, assess particle collision dynamics, and evaluate the efficiency of filtration, considering pressure drop as a fundamental factor in process energy consumption. TPMS infill meshes are coded in a Schwarz P shape using Python, and the Darcy‐Forchheimer equation is employed to determine the permeability and resistance loss coefficient of the infill geometry. The results indicate that the TPMS infill efficiently captures particles while introducing a negligible pressure drop into the system. It is found that a single 40 mm infill configuration is the most efficient, exhibiting a higher collision rate compared to the smaller 20 mm infill configuration and a lower pressure drop compared to the two 20 mm infill configurations in the series. Additionally, this study provides insights into the behavior of continuous fluid flow through TPMS infill in view of scaled‐up implementation, including the presence of recirculation zones that can be exploited to further enhance the collision rate of particles.