Airborne dust can cause engine wear and contribute to engine gas emission. This study developed a novel submicro-fiber filter medium to provide protection to engines against dust. The wet-laid submicro-fiber medium was prepared by a dual-layer paper machine, and its dust loading performance was compared with other filter media during laboratory and field tests. During the laboratory tests, the dust holding capacity of the wet-laid submicro-fiber medium was 48% and 10% higher than that of the standard heavy-duty medium and electrospun submicro-fiber medium, respectively. During the field tests, the pressure drop of the wet-laid submicro-fiber filter was 45% lower than that of the standard heavy-duty filter after 10,000 km of operation. It was found that there were two crucial ways to design a better filter medium for protection against dust. Firstly, the surface loading rather than the depth loading was preferred for dust filtration. The submicro-fiber layer kept large amounts of dust particles from penetrating into the depth of filter medium. Secondly, particles were captured preferably by fibers rather than pores. The unique fibrous structure of the wet-laid submicro-fiber medium made more particle deposition take place on fibers via interception and inertial impaction.

Ambient particulate matter less than 2.5 μm (PM_2.5) can substantially degrade the performance of cars by clogging the air intake filters. The application of nanofibers in air filter paper can achieve dramatic improvement of filtration efficiency with low resistance to air flow. Cellulose nanofibers have gained increasing attention because of their biodegradability and renewability. In this work, the cellulose nanofiber was prepared by Lyocell fiber nanofibrillation via a PFI-type refiner, and the influence of applying a cellulose nanofiber on filter paper was investigated. It was found that the cellulose nanofibers obtained under 1.00 N/mm and 40,000 revolutions were mainly macrofibrils of Lyocell fiber with average fiber diameter of 0.8 µm. For the filter papers with a different nanofiber fraction, both the pressure drop and fractional efficiency increased with the higher fraction of nanofibers. The results of the figure of merit demonstrated that for particles larger than 0.05 µm, the figure of merit increased substantially with a 5% nanofiber, but decreased when the nanofiber fraction reached 10% and higher. It was concluded that the optimal fraction of the cellulose nanofiber against PM_2.5 was 5%. The results of the figure of merit were related to the inhomogeneous distribution of nanofibers in the fibrous structure. The discrepancy of the theoretical and measured pressure drop showed that a higher nanofiber fraction led to a higher degree of fiber inhomogeneity.

A novel high-efficient flame retardant epoxy grafted poly-acrylic resin modified by phosphorus and nitrogen was successfully synthesized by radical grafting polymerization and solution polymerization simultaneously. The flame retardancy of copolymer resin was investigated using thermogravimetric analysis (TGA), cone calorimetric test (CONE), limiting oxygen index (LOI) and so on. The micro-morphology and chemical composition of char formed after a CONE calorimetric test was analyzed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The Kissinger method was used to evaluate the kinetics of thermal decomposition on copolymer resin. The results showed that the flame retardant property of copolymer resin increased with the increase in phosphorus content. With the increase in nitrogen content, however, the flame retardant property first increased and then decreased. The flame retardant property of the resin was the best and the limiting oxygen index could reach 34.3% when the phosphorus content and nitrogen content of the copolymer resin were 6.45 wt% and 2.33 wt%, respectively. Meanwhile, nitrogen-containing compounds will interact with phosphorus-containing compounds to form P-N intermediates during combustion, which have stronger dehydration and carbonization and could further enhance the flame retardant performance of the resin and generate phosphorus-nitrogen synergistic interactions.

NH₃ is a typical alkaline gaseous pollutant widely derived from industrial production and poses great risks to humans and other biota. Metal-organic frameworks (MOFs) have excellent adsorption capacities relative to materials traditionally used to adsorb NH₃. However, in practice, applications of MOFs as adsorbents are restricted because of its powder form. We prepared a polyamide (PA) macroporous polyester substrate using an emulsion template method and modified the surface with polyethylenimine (PEI) to improve the MOF growth efficiency on the substrate. The difficulty of loading the MOF because of the fast nucleation rate inside the PA macroporous polyester substrate was solved using a stepwise impregnation layer-by-layer (LBL) growth method, and a PA-PEI-MOF303(Al) hierarchical pore composite that very efficiently adsorbed NH₃ was successfully prepared. The PA-PEI-MOF303(Al) adsorption capacity for NH₃ was 16.07 mmol·g⁻¹ at 298 K and 100 kPa, and the PA-PEI-MOF303(Al) could be regenerated repeatedly under vacuum at 423 K. The NH₃ adsorption mechanism was investigated by in situ Fourier transform infrared spectroscopy and by performing two-dimensional correlation analysis. Unlike for the MOF303(Al) powder, the formation of multi-site hydrogen bonds between Al–O–Al/C–OH, N–H, –OH, C=O, and NH₃ in PA-PEI-MOF303(Al) was found to be an important reason for efficient NH₃ adsorption. This study will provide a reference for the preparation of other MOF-polymer composites.

Radon is one of the 19 carcinogenic substances identified by the World Health Organization, posing a significant threat to human health and the environment. Properly removing radon under ambient conditions remains challenging. Compared with traditional radon−adsorbent materials such as activated carbon and zeolite, metal–organic framework (MOF) materials provide a high specific surface area, rich structure, and designability. However, MOF material powders demonstrate complications regarding practical use, such as easy accumulation, deactivation, and difficult recovery. Ni−MOF−74 was in situ grown on a porous polyacrylic acid (PA) spherical substrate via stepwise negative pressure impregnation. Ni−MOF−74 was structured as one−dimensional rod−shaped crystals (200–300 nm) in large−pore PA microspheres, whose porous structure increased the diffusion of radon gas. The radon adsorption coefficient of a Ni−MOF−74@PA−polyethyleneimine composite material was 0.49 L/g (293 K, relative humidity of 20%, air carrier). In comparison with pristine Ni−MOF−74 powder, our composite material exhibited enhanced adsorption and longer penetration time. The radon adsorption coefficient of the composite material was found to be from one to two orders of magnitude higher than that of zeolite and silica gel. The proposed material can be used for radon adsorption while overcoming the formation problem of MOF powders. Our preparation approach can provide a reference for the composite process of MOFs and polymers.