Exploring high-performance electrocatalysts for sustainable hydrogen production is an essential prerequisite of a further hydrogen economy. Integrating multiple interfaces in two-component electrocatalysts is expected to be a feasible strategy to optimize the intrinsic electronic structure of hybrid catalysts and improve their catalytic property. Herein, we report a new type of multi-interfacial nickel/tungsten carbide (Ni/WC) hybrid nanoparticles anchored on N-doped carbon sheets (Ni/WC@NC), which can efficiently and robustly catalyze the hydrogen evolution reaction (HER) with striking kinetic metrics in a wide pH range. In 0.5 M H₂SO₄, Ni/WC@NC displays a low overpotential (53 mV at current density of 10 mA cm⁻²), a small Tafel slope (43.5 mV dec⁻¹), a high exchange current density (0.83 mA cm⁻²), as well as excellent stability, outperforming most of the current noble-metal-free electrocatalysts. A series of controlled experiments, DFT calculations and in situ XAS measurements reveal that the remarkable HER activity is mainly attributed to abundant interfaces between Ni and WC domains, which induce a synergistic optimization of the electronic configuration of Ni and WC through electron transfer process from WC to Ni along with potential mass transport, thus promoting the HER kinetics and accelerating the reaction. Our work suggests a potentially powerful interface-engineering strategy for designing high-performance electrocatalysts for the HER.

A N-carbon coated P-modified W ₂ C composite (P-W ₂ C@NC), prepared by annealing a mixture of H ₃ PW ₁₂ O ₄₀ and dicyandiamide, exhibits excellent HER electrocatalytic activity and durability over the whole pH range.

The CO₂reduction reaction on Z-scheme B-doped g-C₃N₄/SnS₂was investigated by DFT, exhibiting a highly efficient photocatalytic activity.

A 3D configuration of high-quality graphene sheets and a polyoxometalate [H₇P₈W₄₈O₁₈₄]³³⁻ showing excellent hydrogen evolution activity at extremely low overpotential.

Surface composition on Ti₃C₂ MXene (0001) surface and its effect on hydrogen evolution reaction are analyzed based on systematic density functional calculations.