The crossed molecular beams reaction of ground state cyano radicals (CN) with diacetylene (HCCCCH) was studied in the laboratory under single collision conditions. Combining the derived center-of-mass translational energy and angular distributions with novel electronic structure calculations, we show that the linear cyanodiacetylene molecule (HCCCCCN) is the sole reaction product. Our study provided no substantiation of two alternative products which have been suggested previously: cyanoacetylene (HCCCN), speculated to be synthesized via the exchange of the ethynyl by the cyano group, and the 1,3-butadiynyl radical (HCCCC), thought to be formed via hydrogen abstraction. The unambiguous identification of cyanodiacetylene formed in an exoergic, barrierless bimolecular reaction of the cyano radical with diacetylene strongly suggests that cyanodiacetylene can be also synthesized via this process in the interstellar medium (cold molecular clouds) and in hydrocarbon-rich atmospheres of planets and their moons such as Titan.

Background: Effects of Tai Chi on people with peripheral neuropathy (PN) are not yet apparent. This systematic review was conducted to evaluate the effects of Tai Chi on postural control in people with PN. Methods: Literature was screened in seven databases for relevant randomized controlled trials. The reports and methodological quality were evaluated. A meta-analysis was performed using RevMan5.4 software. Results: Ten reports were included, involving a total of 344 subjects. The meta-analysis found that Tai Chi therapy for people with PN resulted in a smaller sway area, in the double-leg stance with eyes closed test (SMD = −2.43, I² = 0%), than that observed in the control group, greater distance covered in the six-minute walking test (SMD = −0.46, I² = 49%) and faster performance in the timed-up-and-go test (SMD = 0.68, I² = 50%), than the baseline. Conclusions: Tai chi effectively enhanced dynamic postural control in people with PN. However, no better effects on postural control from Tai Chi than from other rehabilitation approaches were observed in this study. Further high-quality trials are needed to better understand Tai Chi’s effects on individuals with PN.

Balance is a fundamental quality for trampoline athletes, the basis for completing complex skills. We aimed to compare balance control strategies between elite trampolinists (ETs) and sub-elite trampolinists (Sub-ET) by integrating linear and nonlinear center of pressure (COP) measures across stable and unstable surfaces. Twenty-four male athletes (12 ET, 12 Sub-ET) participated. Each participant performed 15-s static standing trials with eyes closed on a firm surface (FI) and a foam surface (FO). COP parameters were extracted, including ellipse area, sway velocity, sway range, and sample entropy (SampEn) in the medio-lateral (ML) and antero-posterior (AP) directions. Repeated-measures ANOVA was applied to examine the effects of group and surface condition. Linear analyses indicated that ET athletes exhibited greater sway amplitudes and faster velocities than Sub-ET athletes, with both groups showing larger sway on FO compared with FI. Nonlinear analyses revealed that ET athletes demonstrated lower SampEn, suggesting more structured and automatized control strategies. ET athletes maintained consistent entropy across both conditions, reflecting stronger adaptability to unstable surfaces. These results emphasize the importance of combining linear and nonlinear measures in balance assessment and suggest that incorporating unstable or trampoline-like surfaces into training may enhance adaptability, improve performance, and reduce injury risk.

In people with peripheral neuropathy (PN), impaired plantar sensation can cause adaptive changes in the central nervous system (CNS), resulting in changes in the standing postural control, which is reflected in the variability of standing output signals. Standard deviation (SD) and entropy are reliable indicators of system variability, especially since entropy is highly sensitive to diseased populations. The relation between SD and entropy, CNS and center of pressure (COP) variability is unclear for people with severe PN. The purpose of this study was to explore the adaptability of the CNS to the severe of PN and its effect on the degree and complexity of COP variability. Here, people with PN were divided into less affected (LA) and more affected (MA) groups based on plantar pressure sensitivity. We studied Hoffmann reflex (H-reflex) and standing balance performance with the control group (n = 8), LA group (n = 10), and MA group (n = 9), recording a 30 s COP time series (30,000 samples) of double-leg standing with eyes open. We observed that the more affected group had less COP complexity than people without PN. There is a significant negative correlation between the SD and sample entropy in people without PN, less affected and more affected. The COP complexity in people without PN was inversely correlated with H-reflex. We concluded that: (1) The complexity of COP variability in patients with severe plantar sensory impairment is changed, which will not affect the degree of COP variability; (2) The independence of the COP entropy in the AP and ML directions decreased, and the interdependence increased in people with PN; (3) Although the CNS of people with PN has a greater contribution to standing balance, its modulation of standing postural control is decreased.