In this work, membranes were synthesized by depositing fluoropolymer coatings onto metal meshes using the hot wire chemical vapor deposition (HW CVD) method. By changing the deposition parameters, membranes with different wetting angles were obtained, with water contact angles for different membranes over a range from 130° ± 5° to 170° ± 2° and a constant oil contact angle of about 80° ± 2°. These membranes were used for the separation of an oil–water emulsion in a simple filtration test. The main parameters affecting the separation efficiency and the optimal separation mode were determined. The results reveal the effectiveness of the use of the membranes for the separation of emulsions of water and commercial crude oil, with separation efficiency values that can reach over 99%. The membranes are most efficient when separating emulsions with a water concentration of less than 5%. The pore size of the membrane significantly affects the rate and efficiency of separation. Pore sizes in the range from 40 to 200 µm are investigated. The smaller the pore size of the membranes, the higher the separation efficiency. The work is of great economic and practical importance for improving the efficiency of the membrane separation of oil–water emulsions. It lays the foundation for future research on the use of hydrophobic membranes for the separation of various emulsions of water and oil products (diesel fuel, gasoline, kerosene, etc.).
A novel, low-temperature process is proposed for the synthesis of the multiferroic compound BiFeO3. It enables the preparation of nanoparticulate material at temperatures as low as 200–250°C. An important role in the low-temperature synthesis of bismuth orthoferrite is played by ammonium nitrate additions and excess bismuth oxide.
1 October 2023 in Journal of Applied Mechanics and Technical Physics
This study demonstrates that the surface roughness of a copper sample can be controlled by treating it with glow discharge plasma. It is established that the main process affecting the morphology and composition of the surface is oxidation. Treatment causes the formation of various copper oxide nano- and microstructures on the surface of a copper sample. It is shown that, in the parameter range studied, the working gas pressure has a more significant effect on the formation of various structures than the glow discharge current density. As a result of the treatment, various stages of the surface oxidation are observed, caused by differences in the surface temperature.
1 June 2023 in Journal of Applied Mechanics and Technical Physics
The possibility of changing the silicon surface morphology at certain glow discharge parameters is shown. It is established that oxidation is the main process influencing the surface morphology during glow discharge plasma treatment. As a result of processing in the investigated parameter range, various stages of the surface oxidation process are observed: the formation of a uniform oxide layer and the formation of nano- and microstructures of silicon oxide. It is shown that these processes lead to surface modification, which acquires stable hydrophilic and superhydrophilic properties.
The process of plasma etching for the formation of a biphilic pattern in a continuous homogeneous fluoropolymer coating on a copper substrate is studied. Argon or oxygen plasma of low frequency ferromagnetic amplified induction discharge is used to etch a fluoropolymer coating. Plasma etching was carried out through a mask with parallel slits. The etching rate in argon plasma was 10 nm/min, the etching rate in oxygen plasma was 60 nm/min. Biphilic surfaces were obtained, consisting of fluoropolymer strips on a copper surface. It has been shown that when using both argon plasma and oxygen plasma, it is possible to create biphilic surfaces by etching a continuous homogeneous fluoropolymer coating through a mask. Moreover, oxygen plasma is better suited for this because it has a higher etching rate and weakly changes the wettability of the surface.
1 December 2021 in Journal of Physics: Conference Series
The present work investigates the application of the plasma of glow discharge to deposit the fluoropolymer coatings. Two series of experiments were carried out in which the influence of pressure and current strength on surface coatings morphology during its surface treatment with glow discharge plasma was investigated. The surface morphology is investigated by a scanning electron microscope (SEM), and the water contact angle (WCA) is measured. The fact that the choice of pressure significantly affects the morphology and properties of the deposited coating is established.