This study investigates the use of crushed glass waste as partial cement replacement in ordinary concretes. Six concrete mixes were designed and prepared: a reference without substitution and five substitution percentages of crushed glass waste ranging from 5% to 25%. The made concrete mix design underwent different tests, namely: slump test, mechanical strength, thermogravimetric analysis (TGA), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) determination and finally, water porosimetry, in order to evaluate the influence of the use of crushed glass waste on the properties of fresh and hardened concrete. Mechanical strengths results show that the use of 15% of the crushed glass waste improves the mechanical strength. TGA analysis confirms this result by highlighting a higher hydration degree. The latter contributes to the reduction of the porosity and, consequently, the mechanical strength increases. Also, it can be caused by the increasing amount of chromium which, if added a little, accelerates the hydration of C3S and leads to an increase of the mechanical strength. The BET technique and porosimetry tests showed that the use of crushed glass waste reduces the global porosity of concrete. This is due to the filling effect of the glass powder.

This article deals with the study of hazardous chromium leaching, stabilized/solidified by cement CEM II after 28 days of curing, in an acidic environment. The mortars subjected to this study were investigated by X-ray diffraction (XRD) characterization to evaluate the influence of chromium waste on their mineralogical structure. In the study range (0.6–1.2%), increasing the mass percentage of Cr₂O₃ in the mortars indicates that chromium accelerates the hydration process and setting of the mortar and increases the mechanical strength of the mortars compared to the control sample. It was observed that the release of chromium during the Toxicity Characteristic Leaching Procedure (TCLP) test and the efficiency of the stabilization/solidification process depended on the initial Cr concentration and the leaching time. The use of XRD allowed the identification of new crystallized phases in the cement matrices, namely, CaCrO₄·2H₂O and chromium–ettringite Ca₆Cr₂(SO₄)₃(OH)₁₂·26H₂O, which confirms the immobilization of chromium and the efficiency of the stabilization/solidification process. In this research, the release mechanism was found to be primarily a surface phenomenon by modeling the experimental data (dissolution or precipitation).

Concrete defects have a significant impact on concrete constructions. These defects should be considered not only aesthetic defects but also structural defects. In this study, a novel Surface Defect Index (SDI) method was developed to quantify the defect volume according to liquids’ penetrating properties by applying ready-mixed plaster (RMP). The SDI refers to the volumetric proportion of all apparent and unapparent defects in a given area of concrete, and it is expressed as a percentage of the total volume affected by defects. The proposed SDI method was validated and tested under various controlled defect configurations. Regardless of the specific characteristics of each defect configuration, the SDI method consistently demonstrated a high level of consistency, repeatability, and reproducibility, with coefficients of variation (CVr and CVR) below 5% and with correlation coefficients of R² = 0.9968. The method succeeded in assessing the surface quality levels through the SDI, demonstrating a significant correlation between this index and the volume of defects. The proposed index was tested on real concrete surfaces, affirming its efficacy in accurately quantifying the volume of surface defects; thus, it can provide an important metric for quality control. Moreover, it provides an excellent evaluation of the quality of concrete surfaces.