Superhydrophobicity on structured surfaces is frequently achieved via the maintenance of liquid-air interfaces adjacent to the trapped air pockets. These interfaces, however, are subject to instabilities due to the Cassie-Baxter-to-Wenzel transition and total wetting. The current work examines in situ liquid-air interfaces on a submerged surface patterned with cylindrical micropores using confocal microscopy. Both the pinned Cassie-Baxter and depinned metastable states are directly observed and measured. The metastable state dynamically evolves, leading to a transition to the Wenzel state. This process is extensively quantified under different ambient pressure conditions, and the data are in good agreement with a diffusion-based model prediction. A similarity law along with a characteristic time scale is derived which governs the lifetime of the air pockets and which can be used to predict the longevity of underwater superhydrophobicity.

Gated ion flow in graphene oxide membranes: Cells are adept at fast, gated ion flow through tailored channels, which is key to many biological processes. Xue et al. developed ion transistors from reduced graphene oxide membranes and observed a field-enhanced diffusivity of the ions (see the Perspective by Hinds). By applying electrical gating, the average surface potential on the graphene layer could be controlled, thus altering the energy barrier for ion intercalation into the channel and leading to very high diffusion rates. The authors observed selective ion transport two orders of magnitude faster than the ion diffusion in bulk water. Science , this issue p. 501 ; see also p. 459

Significance: Instability and collapse of the underwater slippery air mattress hinder its applications, after which the air mattress cannot be recovered even on superhydrophobic surfaces like lotus leaves. Beyond superhydrophobicity, we present the underwater superrepellent capacity of Salvinia leaves, which can efficiently and robustly recover the invalid slippery air mattress by trapping the replenished air to replace the water in the microstructures. The interconnected wedge-shaped grooves on the base are key to the recovery, which spontaneously transport the replenished air to the entire surface governed by a gas wicking effect. Using 3D printing technology, biomimetic artificial Salvinia surfaces are fabricated, which successfully achieves the recovery of the air mattress. This finding will greatly extend the underwater applications of water-repellant surfaces.

Spontaneous imbibition enables the elegant propelling of nano-flows because of the dominance of capillarity at small length scales. The imbibition kinetics are, however, solely determined by the static host geometry, the capillarity, and the fluidity of the imbibed liquid. This makes active control particularly challenging. Here we show for aqueous electrolyte imbibition in nanoporous gold that the fluid flow can be reversibly switched on and off through electric potential control of the solid-liquid interfacial tension, that is, we can accelerate the imbibition front, stop it, and have it proceed at will. Simultaneous measurements of the mass flux and the electrical current allow us to document simple scaling laws for the imbibition kinetics, and to explore the charge transport in the metallic nanopores. Our findings demonstrate that the high electric conductivity along with the pathways for fluid/ionic transport render nanoporous gold a versatile, accurately controllable electrocapillary pump and flow sensor for minute amounts of liquids with exceptionally low operating voltages.