This publication presents a series of data of one of the most difficult chemical processes to implement in industrial conditions. Obtaining soda using the Solvay technique is a process with a world volume of about 28 Tg per year. The process is extremely physico-chemically complex and environmentally burdensome. The paper presents information on a multi-component system containing three phases with a chemical reaction. Calculations for such systems and their engineering are very complicated, but the authors show how the results of this work can be applied. This paper also describes modifications of the soda process to minimize the environmental burden and minimize the production input of Na₂CO₃. The modifications were beneficial in reducing CO₂ emissions and increased the efficiency of the soda process, resulting in a measurable financial benefit. At the scale of the plant where the experiment was carried out, this reduction in CO₂ emissions amounts to 7.93 Gg per year.

The kick-off process is an important aspect of the proper operation of an agricultural biogas plant. At this stage, various operational problems may arise, mainly related to the stabilization of the fermentation process and reaching the full biogas production capacity. This paper presents the results of research on the kick-off of the fermentation process carried out on three selected biogas plants located in Poland. For the experiments, titration, potentiometric, and spectroscopic methods (ICP-MS) were used. The biogas plants during the kick-off period operated on the following substrates: a mixture of cattle and pig manure, corn silage, and whey liquor. Special attention was paid to the dosing process of the formulation developed by the authors (CMP-S1) containing Mo, Co, Ni, Se, and Mn for the fermentation chambers, to which the mixture of the selected microelements was not dosed. The study was carried out under real conditions on an engineering scale. The study showed that supplementing a dedicated mixture of microelements (DMM) in the first days of fermentation chamber kick-off has a positive effect on stabilizing the methane fermentation process and allows a faster and higher loading of fermenters with dry organic matter. The above translates into shortening the time (by more than half) of the kick-off process in the fermentation chamber, as well as brining about a significant reduction in costs.

The development of renewable energy sources is one of the most important paths for today’s economy to follow. Currently, the process of obtaining energy from the combustion of methane extracted by methane fermentation is gaining importance. To improve its efficiency and the speed of the fermentation process and enzyme activation, this study analyzed the effect of the addition of zinc as a micronutrient to fermentation processes using corn silage. The zinc concentration in the fermenter required to stimulate fermentation processes was determined. Studies were conducted to determine inhibitory and toxic concentrations. The determination of the influence of zinc ions on the VFA profile and the value of the carbon-to-methane conversion coefficient is important for the economic aspects of obtaining biogas with the highest methane content. The carbon-to-methane conversion factor and the effect of the addition of zinc on the value of this factor were determined. During the course of the research, modern analytical chemistry methods and techniques were used. The purpose of this study was to determine the optimal concentration of zinc in the digester to maximize the methane yield of the fermentation process.