CuO/CuO2/Cu nanoparticles were prepared by sonochemical combined thermal synthesis method and used as new photocatalyst for simultaneous photocatalytic degradation of safranin O (SO) and methylene blue (MB) dyes in rotating packed bed reactor equipped to blue light emitting diode (LED). The physicochemical properties of the synthesized CuO/Cu2O/Cu nanoparticles were investigated by XRD, SEM and DRS analysis. The band-gap of the prepared CuO/Cu2O/Cu-NPs was estimated to be about 1.42eV which is appropriate for photodegradation process under blue light irradiation. In rotating packed bed reactors, two key parameters are very important, one high centrifugal field and other porous media, which intensify mass transfer operation leads to photodegradation improvement. The maximum photodegradation efficiency was obtained at pH of 6 and subsequently the effects of CuO/Cu2O/Cu-NPs dosage, rotational speed, initial dyes concentration, flow rate and reaction time were studied by central composite design (CCD) and optimized values were found to be 0.3g/L, 900rpm, 10mg/L of both dyes, 0.3L/min and 90min, respectively. Finally, results showed that synergistic effects induced by forming Cu2O/CuO heterojunction containing Cu-NPs co-cocatalyst greatly accelerate electron transfer and effectively retard the reduction of CuO by photo-generated electrons.

An efficient simultaneous sonophotocatalytic degradation of trypan blue (TB) and vesuvine (VS) using Ag3PO4/Bi2S3-HKUST-1-MOF as a novel visible light active photocatalyst was carried out successfully in a continuous flow-loop reactor equipped to blue LED light. Ag3PO4/Bi2S3-HKUST-1-MOF with activation ability under blue light illumination was synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), photoluminescence (PL) and diffuse reflectance spectra (DRS). The effect of operational parameters such as the initial TB and VS concentration (5-45mg/L), flow rate (30-110mL/min), irradiation and sonication time (10-30min), pH (3-11) and photocatalyst dosage (0.15-0.35g/L) has been investigated and optimized using central composite design (CCD) combined with desirability function (DF). Maximum sonophotodegradation percentage (98.44% and 99.36% for TB and VS, respectively) was found at optimum condition set as: 25mg/L of each dye, 70mL/min of solution flow rate, 25min of irradiation and sonication time, pH 6 and 0.25g/L of photocatalyst dosage. At optimum conditions, synergistic index value was obtained 2.53 that indicated the hybrid systems including ultrasound irradiation and photocatalysis have higher efficiency compared with sum of the individual processes.

A new composite of mesoporous materials, HKUST-1 metal organic framework and SBA-15, was synthesized and applied to the simultaneous visible-light-driven photodegradation of a binary dye mixture of safranin O and malachite green.

BiPO ₄ /Bi ₂ S ₃ -HKUST-1-MOF as a novel blue light active photocatalyst was synthesized and characterized by X-ray XRD, SEM, PL, BET, BJH and DRS.

A new hybrid material composed of BiVO₄ and HKUST-1 MOF (HKUST-1-MOF–BiVO₄), which is active under blue light irradiation, was synthesized and characterized by XRD, FE-SEM, BET, BJH, EDS and DRS analysis.