Ionic liquids (ILs) are recognized as a possible replacement of traditional organic solvents, and ILs have been widely applied to extract various compounds. The present work aims to extract ginsenosides from Panax ginseng flower buds using aqueous ionic liquid based ultrasonic assisted extraction (IL-UAE). The extraction yields of 1-alkyl-3-methylimidazolium ionic liquids with different anions and alkyl chains were evaluated. The extraction parameters of eight ginsenosides were optimized by utilizing response surface methodology (RSM). The model demonstrated that a high yield of total ginsenosides could be obtained using IL-UAE, and the optimum extraction parameters were 0.23 M [C₄mim][BF₄], ultrasonic time of 23 min, temperature of extraction set to 30 °C, and liquid-solid ratio of 31:1. After that, an aqueous biphasic system (ABS) was used to separate ginsenosides further. The nature and concentration of salt, as well as the value of pH in ionic liquid were evaluated, and the optimal conditions (6.0 mL IL extract, 3 g NaH₂PO₄, and pH 5.0) were obtained. The preconcentration factor was 2.58, and extraction efficiency reached 64.53%. The results indicate that as a simple and efficient method, an IL-UAE-ABS can be considered as a promising method for extracting and separating the natural active compounds from medicinal herbs.

Starch, alginate, and poly(N-isopropylacrylamide) (PNIPAAm) were combined to prepare a semi-interpenetrating network (IPN) hydrogel with temperature sensitivity. Calcium chloride was used as cross-linking agent, the non-toxigenic Aspergillus flavus spores were successfully encapsulated as biocontrol agents by the method of ionic gelation. Characterization of the hydrogel was performed by Fourier-transform infrared spectroscopy (FTIR), scanning electron micrograph (SEM), and thermogravimetry analysis (TGA). Formulation characteristics, such as entrapment efficiency, beads size, swelling behavior, and rheological properties were evaluated. The optical and rheological measurements indicated that the lower critical solution temperature (LCST) of the samples was about 29–30 °C. TGA results demonstrated that the addition of kaolin could improve the thermal stability of the semi-IPN hydrogel. Morphological analysis showed a porous honeycomb structure on the surface of the beads. According to the release properties of the beads, the semi-IPN hydrogel beads containing kaolin not only have the effect of slow release before peanut flowering, but they also can rapidly release biocontrol agents after flowering begins. The early flowering stage of the peanut is the critical moment to apply biocontrol agents. Temperature-sensitive hydrogel beads containing kaolin could be considered as carriers of biocontrol agents for the control of aflatoxin in peanuts.

For the wise use of fungal biocontrol and metalaxyl fungicide, starch–alginate-based formulations have been developed by encapsulating metalaxyl and non-toxigenic Aspergillus flavus spores simultaneously in the form of microspheres using calcium chloride as a cross-linking agent. The formulations were characterized by Fourier transform infrared spectroscopy (FTIR), a scanning electron micrograph (SEM), and thermogravimetry (TGA). Formulation characteristics, including the bead size, entrapment efficiency, swelling ratio of the beads, and rheological properties, were analyzed. The release behavior of beads with different formulations was evaluated. The addition of kaolin and rice husk powder in starch–alginate beads retarded the release profile of spores and metalaxyl. The release of the active ingredient from starch–alginate–kaolin beads and starch–alginate–rice husk powder beads occurred in both a controlled and sustained manner. Additionally, the release rate decreased with the increase of kaolin or rice husk powder content. The beads added with kaolin were slower than the release of rice husk powder. In comparison, spores released slower and lasted longer than metalaxyl. The starch–alginate–kaolin formulations could be used as controlled release material in the field of biocontrol and reduce the harm of fungicides to the environment.

The consumption of agricultural products contaminated with mycotoxins poses a significant threat to the health of both humans and animals. Maize frequently becomes contaminated with toxic fungi while it is still growing in the field. Therefore, more proactive measures should be implemented to reduce mycotoxin levels during the storage and processing of maize after harvest. This article analyzes the prevalent mycotoxins found in maize, specifically aflatoxins, ochratoxins, trichothecenes, fumonisins, and zearalenone. The study provides a comprehensive analysis of the occurrence of mycotoxins in maize during storage, as well as fate analysis of them during processing. It summarizes the impacts of storage time, environmental conditions, storage methods, and agricultural practices on mycotoxin occurrence during storage in the post-harvest period. Furthermore, the different distribution of mycotoxins across various fractions during both dry- and wet-milling processes in the post-harvest processing period is analyzed. Additionally, the strategies to control mycotoxins in maize are also proposed during the post-harvest period. This review offers valuable insights for future research on mycotoxin contamination in maize during the post-harvest period.

Grain moisture is one of the key indexes of grain quality, and acquiring an accurate moisture value is critical for grain storage security. However, the sensors used in the traditional methods for testing grain moisture are based on capacitance, microwave, or radio-frequency methods and still exhibit low accuracy and instability because they are susceptible to the temperature, moisture, and micro gas flow of the air in the granary. In this study, we employed a new design for a radio-frequency moisture sensor for grain. The structure of the sensor is based on the difference method and consists of two parallel probe units. These units are at different distances to the tested grain, resulting in different sensitivities in the moisture measurements. Through a phase difference operation on the test signals, the disturbance variable was reduced. The specific size of the two parallel probes was confirmed by calculation and simulation using High Frequency Structure Simulator (HFSS) software. The simulated and measured parameters of a prototype sensor agreed well. The linear relationship yielded a correlation coefficient of 0.9904, and the average error of the moisture testing was within ±0.3% under the conditions where the VSWR (voltage standing wave ratio) value and return losses were 1.5896 and −20 dB, respectively, at a measured central frequency of 100 MHz. The results indicate that the performance of the sensor was excellent.