Room-temperature phosphorescence materials are manufactured by a facile click reaction between phosphor and polymer.

It remains a great challenge to engineer materials with strong and stable interactions for the simultaneously mechanical-robust and room temperature phosphorescence-efficient materials. In this work, we demonstrate a covalent cross-linking strategy to engineer mechanical-robust room temperature phosphorescence materials through the B–O click reaction between chromophores, polyvinyl alcohol matrix and inorganic layered double hydroxide nanosheets. Through the covalent cross-linkage between the organic polyvinyl alcohol and inorganic layered double hydroxide, a polymeric composite with ultralong lifetime up to 1.45 s is acquired based on the inhibited non-radiative transition of chromophores. Simultaneously, decent mechanical strength of 97.9 MPa can be realized for the composite materials due to the dissipated loading stress through the covalent-bond-accommodated interfacial interaction. These cross-linked composites also exhibit flexibility, processability, scalability and phosphorescence responses towards the mechanical deformation. It is anticipated that the proposed covalent click reaction could provide a platform for the design and modulation of composites with multi-functionality and long-term durability.

The adsorption of dyes in contaminated water is an effective approach to solving the environmental crisis. Layered double hydroxide (LDH) and its calcinated product layered double oxide (LDO) show great potential as adsorbents. However, the conventional preparation of LDH or LDO typically suffers from aggregation and blocked active sites, hampering the adsorption efficiency of the adsorbent. Herein, three-dimensional, hollow MgFe-LDO spheres were constructed through the sacrifice of a carbon template. The hollow structure and the monodisperse state provided MgFe-LDO with sufficient microchannels and abundant active sites for adsorption. Through the memory effect of LDO, the anion methyl blue (MB) can be effectively adsorbed with a high uptake capacity of 398 mg g⁻¹. Isotherm simulations demonstrated the monolayer adsorption of MB and the heterogeneous surfaces of the reconstructed LDHs. Moreover, the adsorbents can be recycled and reutilized at least five times through magnetic separation followed by calcination. Our proposed strategy is expected to provide new possibilities for the construction of adsorbents with well-controlled architecture and abundant active sites to deal with anionic pollutants.