This study investigates the pyrolysis and adsorption properties of biochar derived from coconut shell (BC-CS), rice husk (BC-RH), and cow manure (BC-CM) under varying thermal treatment conditions. Biochar samples were produced at 800 °C with residence times ranging from 0 to 60 min. Their characteristics were analyzed using their Brunauer–Emmett–Teller (BET) surface area, total pore volume, and pore diameter measurements. BC-CM exhibited the highest BET surface area of 263.3 m²/g and a total pore volume of 0.164 cm³/g, while BC-RH and BC-CS showed maximum BET surface areas of 220.62 m²/g and 197.38 m²/g, respectively. Nitrogen adsorption–desorption isotherms revealed distinct microporous and mesoporous structures, with BC-CM demonstrating superior adsorption capacity across all relative pressures. The adsorption kinetics of methylene blue (MB) were examined at initial concentrations of 1 ppm, 5 ppm, and 10 ppm, with varying biochar doses (0.1 g, 0.3 g, and 0.5 g). The results showed that the adsorption rate constant (k) decreased with higher initial MB concentrations, while the equilibrium adsorption capacity (q_e) increased. BC-CM achieved the highest q_e of 2.18 mg/g at 10 ppm and a 0.5 g dose, followed by BC-RH-800-45 (1.145 mg/g) and BC-CS (0.340 mg/g). The adsorption process was well described by a pseudo-second-order kinetic model, indicating chemisorption as the dominant mechanism. Increasing biochar doses improved MB removal efficiency, highlighting the dose-dependent nature of adsorption. These findings underscore the importance of optimizing pyrolysis parameters to enhance biochar’s adsorption performance and identify key factors influencing its effectiveness in environmental applications.

This study examines the pyrolysis of agricultural residues, namely, coconut shells, rice husks, and cattle manure, in a vertical fixed-bed reactor at varying temperatures from 300 to 800 degrees Celsius for biochar production. The research aimed to evaluate the potential of biochar as biofuels, adsorbents, and soil amendments. Proximate, ultimate, and elemental analyses were conducted to determine their composition and caloric values. Several analytical techniques were used in the physical and chemical characterization of the biochar (SEM, FTIR, BET). The results indicated that the highest S_BET values were achieved under different conditions for each biochar: 89.58 m²/g for BC-CS-700, 202.39 m²/g for BC-RH-600, and 42.45 m²/g for BC-CD-800. Additionally, all three biochars exhibited the highest caloric values at 600 °C. The results showed that 600 °C is the general optimal temperature to produce biochar from an assortment of biomass materials, considering their use for a variety of purposes. BC-CS-800 had the highest elemental carbon content at 93%, accompanied by a relative decrease in oxygen content. The van Krevelen diagram of biochar products shows that biochars derived from coconut shells and rice husks are suitable for use as fuels. Furthermore, FTIR analysis revealed the presence of oxygen-containing functional groups on the biochar surface, enhancing their pollutant adsorption capabilities. This study provides valuable insights into the scalable and environmentally sustainable production of biochar, emphasizing its role in improving soil quality, increasing energy density, and supporting sustainable agricultural practices.

The residue remaining after the water extraction of soapberry pericarp from a biotechnology plant was used to produce a series of biochar products at pyrolytic temperatures (i.e., 400, 500, 600, 700 and 800 °C) for 20 min plant was used to produce a series of biochar products. The effects of the carbonization temperature on the pore and chemical properties were investigated by using N₂ adsorption–desorption isotherms, energy dispersive X-ray spectroscopy (EDS) and Fourier-transform infrared spectroscopy (FTIR). The pore properties of the resulting biochar products significantly increased as the carbonization temperature increased from 700 to 800 °C. The biochar prepared at 800 °C yielded the maximal BET surface area of 277 m²/g and total pore volume of 0.153 cm³/g, showing that the percentages of micropores and mesopores were 78% and 22%, respectively. Based on the findings of the EDS and the FTIR, the resulting biochar product may be more hydrophilic because it is rich in functional oxygen-containing groups on the surface. These results suggest that soapberry pericarp can be reused as an excellent precursor for preparing micro-mesoporous biochar products in severe carbonization conditions.

Despite being a limited resource, pollution, poor management, and other drivers like climate change make available water unsuitable and insufficient for human consumption and ecosystem maintenance. Therefore, a transdisciplinary approach is needed for managing this precious resource. The overall aim of this paper is to address water inequalities and improve human well-being using an integrated approach of key informant interviews, hydrological modeling, and the payment of ecosystem services (PES) scheme in Pinglin District, Taiwan. This site is an upstream area of Feicui Reservoir, which protects the downstream tap water supply. Key informant interviews were conducted to identify the gaps in and challenges to water resource management. This was followed by a scenario-based hydrological simulation using a Water Evaluation and Planning (WEAP) tool to project future water quality by the year 2050 (using biochemical oxygen demand and total coliform content as key indicator parameters) and to trace the factors responsible for water pollution. Survey analysis of key informant interviews depicts that this area is facing several challenges, such as lack of water infrastructure, agricultural subsidy, construction restrictions, etc., which cumulatively cause water scarcity in the upstream regions. On the other hand, hydrological simulation results show that population decline and climate change under an RCP 8.5 scenario will have an enormous negative impact on water quality. The concentrations of BOD and E. coli in river water will expand by 110.1% and 117.3%, respectively, by 2050 compared to 2018. Finally, the results of the study suggest that the PES scheme can play a positive role in enabling integrated water resource management. For example construction of a small-scale wastewater treatment plant in the upstream area will reduce the total E. coli concentration by up to 90%. While the initial cost of construction will be taken care of by the government, the operation and management cost of this infrastructure will be covered by people living downstream, who need to pay only $0.10 per year per person. The obtained results should be vital for both the stakeholders and decision-makers in this region.

The coffee industry generates huge quantities of waste throughout its production and consumption globally. This study explores the application of circular economy principles to transform coffee into useful resources to reduce the coffee industry's environmental impact and enhance its sustainability. A mixed-methods case study design was employed, combining semi-structured interviews with senior officials and department representatives from King's Ground Biotech Co., Ltd., alongside a survey targeting industry practitioners and the public. The findings demonstrate that upcycling coffee waste has significant environmental benefits in terms of waste reduction to landfills and carbon savings, in addition to providing new revenue streams for businesses. However, efforts to scale up such practices are hampered by feedstock consistency issues, logistical inefficiencies, and regulatory barriers. Implementing circular economy practices can drive sustainability in the coffee sector, an advancement that can influence policy and industry practice and enable the coffee sector to create new economic opportunities.

In this work, a novel biomass, the extraction residue of Sapindus pericarp (SP), was torrefied by using an electronic oven under a wide range of temperature (i.e., 200–320 °C) and residence times (i.e., 0–60 min). From the results of the thermogravimetric analysis (TGA) of SP, a significant weight loss was observed in the temperature range of 200–400 °C, which can be divided into the decompositions of hemicellulose (major)/lignin (minor) (200–320 °C) and cellulose (major)/lignin (minor) (320–400 °C). Based on the fuel properties of the feedstock SP and SP-torrefied products, the optimal torrefaction conditions can be found at around 280 °C for holding 30 min, showing that the calorific value, enhancement factor and energy yield of the torrefied biomass were enhanced to be 28.60 MJ/kg, 1.36 and 82.04 wt%, respectively. Consistently, the values of the calorific value, carbon content and molar carbon/hydrogen (C/H) ratio indicated an increasing trend at higher torrefaction temperatures and/or longer residence times. The findings showed that some SP-torrefied solids can be grouped into the characteristics of a lignite-like biomass by a van Krevelen diagram for all the SP-torrefied products. However, the SP-torrefied fuels would be particularly susceptible to the problems of slagging and fouling because of the relatively high contents of potassium (K) and calcium (Ca) based on the analytical results of the energy dispersive X-ray spectroscopy (EDS).