The subclass of multi resonant thermally activated delayed fluorescent emitters (MR-TADF) containing boron atoms has garnered significant attention in the field of organic light emitting diode (OLED) research. Among boron-basedMR-TADFemitters, double boron-embeddedMR-TADF(DB-MR-TADF) emitters show excellent electroluminescence performances with high photoluminescence quantum yields, narrow band emission, and beneficially small singlet-triplet energy levels in all the full-color gamut regions. This article reviews recent progress inDB-MR-TADFemitters, with particular attention to molecular design concepts, synthetic routes, optoelectronic properties, and OLED performance, giving future prospects for real-world applications.

The hunt for narrow-band emissive pure organic molecules capable of harvesting both singlet and triplet excitons for light emission has garnered enormous attention to promote the advancement of organic light-emitting diodes (OLEDs). Over the past decade, organic thermally activated delayed fluorescence (TADF) materials based on donor (D)/acceptor (A) combinations have been researched for OLEDs in wide color gamut (RGB) regions. However, due to the strong intramolecular charge-transfer (CT) state, they exhibit broad emission with full-width-at-half maximum (FWHM) > 70 nm, which deviates from being detrimental to achieving high color purity for future high-end display electronics such as high-definition TVs and ultra-high-definition TVs (UHDTVs). Recently, the new development in the sub-class of TADF emitters called multi-resonant TADF (MR-TADF) emitters based on boron/nitrogen atoms has attracted much interest in ultra-high definition OLEDs. Consequently, MR-TADF emitters are appeal to their potentiality as promising candidates in fabricating the high-efficient OLEDs due to their numerous advantages such as high photoluminescence quantum yield (PLQY), unprecedented color purity, and narrow bandwidth (FWHM ≤ 40 nm). Until now many MR-TADF materials have been developed for ultra-gamut regions with different design concepts. However, most MR-TADF-OLEDs showed ruthless external quantum efficiency (EQE) roll-off characteristics at high brightness. Such EQE roll-off characteristics were derived mainly from the low reverse intersystem crossing (k_RISC) rate values. This feature article primarily focuses on the design strategies to improve k_RISC for MR-TADF materials with some supportive strategies including extending charge delocalization, heavy atom introduction, multi-donor/acceptor utilization, and a hyperfluorescence system approach. Furthermore, the outlook and prospects for future developments in MR-TADF skeletons are described.

Increased interest in chiral functional dyes has stimulated activity in the field of boron-containing helicenes over the past few years. Despite the fact that the introduction of boron endows π-conjugated scaffolds with attractive electronic and optical properties, boron helicenes have long remained underdeveloped compared to other helicenes containing main group elements. The main reason was the lack of reliable synthetic protocols to access these scaffolds. The construction of boron helicenes proceeds against steric strain, and thus the methods developed for planar systems have sometimes proven ineffective in their synthesis. Recent advances in the general boron chemistry and the synthesis of strained derivatives have opened the way to a wide variety of boron-containing helicenes. Although the number of helically chiral derivatives is still limited, these compounds are currently at the forefront of emissive materials for circularly-polarized organic light-emitting diodes (CP-OLEDs). Yet the design of good emitters is not a trivial task. In this perspective, we discuss a number of requirements that must be met to provide an excellent emissive material. These include chemical and configurational stability, emission quantum yields, luminescence dissymmetry factors, and color purity. Understanding of these parameters and some structure–property relationships should aid in the rational design of superior boron helicenes. We also present the main achievements in their synthesis and point out niches in this area, e.g. stereoselective synthesis, necessary to accelerate the development of this fascinating class of compounds and to realize their potential in OLED devices and in other fields.

Pure organic molecules based thermally activated delayed fluorescence (TADF) emitters have been successfully developed in recent years for their propitious application in highly efficient organic light emitting diodes (OLEDs). In the case of orange red emitters, the non‐radiative process is known to be a serious issue due to its lower lying singlet energy level. However, recent studies indicate that there are tremendous efforts put to develop efficient orange red TADF emitters. In addition, the external quantum efficiency (EQE) of heteroaromatic based orange red TADF OLEDs surpassed 30 %. Such heteroaromatic type emitters showed wide emission spectra; therefore, more attention is being paid to develop highly efficient orange red TADF emitters along with good color purity. Herein, the recent progress of orange red TADF emitters based on molecular structures, such as cyanobenzene, heteroaromatic, naphthalimide, and boron‐based acceptors, are reviewed. Further, our insight on these acceptors has been provided by their photophysical studies and device performances. Future perspectives of orange red TADF emitters for real practical applications are discussed.

Over the decade, there have been developments in purely organic thermally activated delayed fluorescent (TADF) materials for organic light-emitting diodes (OLEDs). However, achieving narrow full width at half maximum (FWHM) and high external quantum efficiency (EQE) is crucial for real display industries. To overcome these hurdles, hyperfluorescence (HF) technology was proposed for next-generation OLEDs. In this technology, the TADF material was considered a sensitizing host, the so-called TADF sensitized host (TSH), for use of triplet excitons via the reverse intersystem crossing (RISC) pathway. Since most of the TADF materials show bipolar characteristics, electrically generated singlet and triplet exciton energies can be transported to the final fluorescent emitter (FE) through Förster resonance energy transfer (FRET) rather than Dexter energy transfer (DET). This mechanism is possible from the S₁ state of the TSH to the S₁ state of the final fluorescent dopant (FD) as a long-range energy transfer. Considering this, some reports are available based on hyperfluorescence OLEDs, but the detailed analysis for highly efficient and stable devices for commercialization was unclear. So herein, we reviewed the relevant factors based on recent advancements to build a highly efficient and stable hyperfluorescence system. The factors include an energy transfer mechanism based on spectral overlapping, TSH requirements, electroluminescence study based on exciplex and polarity system, shielding effect, DET suppression, and FD orientation. Furthermore, the outlook and future positives with new directions were discussed to build high-performance OLEDs.