Streams, rivers, lakes, and other inland waters are important agents in the coupling of biogeochemical cycles between continents, atmosphere, and oceans. The depiction of these roles in global‐scale assessments of carbon (C) and other bioactive elements remains limited, yet recent findings suggest that C discharged to the oceans is only a fraction of that entering rivers from terrestrial ecosystems via soil respiration, leaching, chemical weathering, and physical erosion. Most of this C influx is returned to the atmosphere from inland waters as carbon dioxide (CO₂) or buried in sedimentary deposits within impoundments, lakes, floodplains, and other wetlands. Carbon and mineral cycles are coupled by both erosion–deposition processes and chemical weathering, with the latter producing dissolved inorganic C and carbonate buffering capacity that strongly modulate downstream pH, biological production of calcium‐carbonate shells, and CO₂ outgassing in rivers, estuaries, and coastal zones. Human activities substantially affect all of these processes.

The characteristics of the sediment transported by rivers (e.g. sediment flux, grain size distribution – GSD) dictate whether rivers aggrade or erode their substrate. They also condition the architecture and properties of sedimentary successions in basins. In this study, we investigate the relationship between landscape steepness and the grain size of hillslope and fluvial sediments. The study area is located within the Feather River basin in northern California, and studied basins are underlain exclusively by tonalite lithology. Erosion rates in the study area vary over an order of magnitude, from >250 mm ka⁻¹ in the Feather River canyon to <15 mm ka⁻¹ on an adjacent low-relief plateau. We find that the coarseness of hillslope sediment increases with increasing hillslope steepness and erosion rates. We hypothesise that, in our soil samples, the measured 10-fold increase in D₅₀ and doubling of the amount of fragments larger than 1 mm when slope increases from 0.38 to 0.83 m m⁻¹ is due to a decrease in the residence time of rock fragments, causing particles to be exposed for shorter periods of time to processes that can reduce grain size. For slopes in excess of 0.7 m m⁻¹, landslides and scree cones supply much coarser sediment to rivers, with D₅₀ and D₈₄ more than one order of magnitude larger than in soils. In the tributary basins of the Feather River, a prominent break in slope developed in response to the rapid incision of the Feather River. Downstream of the break in slope, fluvial sediment grain size increases, due to an increase in flow competence (mostly driven by channel steepening) as well as a change in sediment source and in sediment dynamics: on the plateau upstream of the break in slope, rivers transport easily mobilised fine-grained sediment derived exclusively from soils. Downstream of the break in slope, mass wasting processes supply a wide range of grain sizes that rivers entrain selectively, depending on the competence of their flow. Our results also suggest that, in this study site, hillslopes respond rapidly to an increase in the rate of base-level lowering compared to rivers.