Nickel oxide is one of the highly promising semiconducting materials, but its large band gap (3.7 to 4 eV) limits its use in practical applications. Here we report the effect of nickel/oxygen vacancies and interstitial defects on the near-band-edge (NBE) and deep-level-emission (DLE) in various sizes of nickel oxide (NiO) nanoparticles. The ultraviolet (UV) emission originated from excitonic recombination corresponding near-band-edge (NBE) transition of NiO, while deep-level-emission (DLE) in the visible region due to various structural defects such as oxygen vacancies and interstitial defects. We found that the NiO nanoparticles exhibit a strong green band emission around ~2.37 eV in all samples, covering 80% integrated intensity of PL spectra. This apparently anomalous phenomenon is attributed to photogenerated holes trapped in the deep level oxygen vacancy recombining with the electrons trapped in a shallow level located just below the conducting band.

We report the phonon and magnetic properties of various well-stabilized Co₃O₄ nanoparticles. The net valence in cobalt (II)/(III) cation can be obtained by subtracting the Co²⁺ ions in tetrahedral interstices and Co³⁺ ions in the octahedral interstices, respectively, which will possess spatial inhomogeneity of its magnetic moment via Co²⁺ in tetrahedra and Co³⁺ in octahedral configurations in the normal spinel structure. Furthermore, the distribution of Co²⁺/Co³⁺ governed by various external (magnetic field and temperature) and internal (particle size and slightly distorted CoO₆ octahedra) sources, have led to phenomena such as a large redshift of phonon-phonon interaction and short-range magnetic correlation in the inverse spinel structure. The outcome of our study is important in terms of the future development of magnetic semiconductor spintronic devices of Co₃O₄.

The nanosized effects of short-range multimagnon excitation behavior and short-circuit diffusion in NiO nanowalls synthesized using the Ni grid thermal treatment method were observed. The energy dispersive spectroscopy mapping technique was used to characterize the growth mechanism, and confocal Raman scattering was used to probe the antiferromagnetic exchange energy J ₂ between next-nearest-neighboring Ni ions in NiO nanowalls at various growth temperatures below the Neel temperature. This study shows that short spin correlation leads to an exponential dependence of the growth temperatures and the existence of nickel vacancies during the magnon excitation. Four-magnon configurations were determined from the scattering factor, revealing a lowest state and monotonic change with the growth temperature. PACS: 75.47.Lx; 61.82.Rx; 75.50.Tt; 74.25.nd; 72.10.Di

The air annealing induced grain growth from nano to microscale and a transformation sequence from Bi → β-Bi₂O₃ → γ-Bi₂O₃ → α-Bi₂O₃ was evident. All the annealed samples are oxygen-deficient, resulting in the appearance of a strong red emission band.