The NO₂ sensing performance of SnO₂ nanowires was enhanced through the formation of oxygen vacancies which were generated by laser irradiation.

A NO ₂ gas sensor integrated with two-dimensional covalent organic nanosheets shows highly sensitive and reliable NO ₂ sensing performance even at relatively high humidity levels. The excellent water-repelling ability originates from the superhydrophobic nature of CON surfaces.

The bandgap-dependent performance of covalent organic nanosheets (CONs) as sodium-ion battery anode materials was probed by inclusion of electron-deficient benzothiadiazole (BT) units into their network. Conjugation of BT units with electron-rich moieties afforded low-bandgap materials, and a self-assembled CON morphology with a large number of insertion sites for Na⁺ ions was realized via solvothermal Stille cross-coupling. The bandgap dependence of Na⁺ storage capacity was probed by the synthesis and characterization of large-bandgap CONs, which were subsequently compared to low-bandgap CONs in terms of electrochemical behavior. Four different CONs were investigated in total to reveal that the Na⁺ storage capacity can be improved by increasing the charge carrier conductivity via the inclusion of BT units, while the surface area can be controlled by maintaining the material backbone. The electrode with a solvothermally prepared low-bandgap CON demonstrated stable rate capability and cycling performance while exhibiting highly enhanced reversible discharge capacity (∼450 mA h g⁻¹) after 30 cycles at a scan rate of 100 mA g⁻¹. To the best of our knowledge, this discharge capacity is among the best values reported so far for organic electrodes prepared without thermal treatment.

A new type of organic framework was synthesized via two different routes, a solvothermal reaction and conventional refluxing, via a Stille cross-coupling reaction. The resulting products from the two routes consisted of graphene-like nanosheets. Additionally, the morphologies of such polymer networks were controlled based on the synthetic route and solvent used for film formation.