In the framework of the “Multidisciplinary Optimization and Regulations for Low-boom and Environmentally Sustainable Supersonic aviation” project, pursued by a consortium of European government and academic institutions, coordinated by Politecnico di Torino under the European Commission Horizon 2020 financial support, the Italian Aerospace Research Centre is computationally investigating the high-pressure hydrogen/air kinetic combustion in the operative conditions typically encountered in supersonic aeronautic ramjet engines. This task is being carried out starting from the zero-dimensional and one-dimensional chemical kinetic assessment of the complex and strongly pressure-sensitive ignition behavior and flame propagation characteristics of hydrogen combustion through the validation against experimental shock tube and laminar flame speed measurements. The 0D results indicate that the kinetic mechanism by Politecnico di Milano and the scheme formulated by Kéromnès et al. provide the best matching with the experimental ignition delay time measurements carried out in high-pressure shock tube strongly argon-diluted reaction conditions. Otherwise, the best behavior in terms of laminar flame propagation is achieved by the Mueller scheme, while the other investigated kinetic mechanisms fail to predict the flame speeds at elevated pressures. This confirms the non-linear and intensive pressure-sensitive behavior of hydrogen combustion especially in the critical high-pressure and low-temperature region which is hard to be described by a single all-encompassing chemical model.

According to the latest report of the Intergovernmental Panel on climate change, aviation contributes to only about 2% to anthropogenic global greenhouse gas (GHG) emissions. However, in view of the growing market demand and the dramatic reductions in other transport sectors, including maritime and automotive, the aviation sector’s percentage impact on global GHG emissions is expected to reach 50% of the transport share by 2040. High-speed aviation exploiting liquid hydrogen as the propellant can represent a valuable solution toward the decarbonization of the sector. However, to avoid jeopardizing the dream of a new generation of high-speed aircraft, it will be necessary to introduce non-CO₂ emissions estimations beginning with the design process. To unlock the possibility of anticipating the nitrogen oxides emissions estimation, the authors developed the hydrogen and high-speed P₃-T₃ methodology (H2-P₃T₃), an evolution of the widely used P₃-T₃ method, properly conceived to support (i) innovative air-breathing propulsive systems for supersonic and hypersonic flights and (ii) greener fuels, such as hydrogen. This paper presents a step-by-step approach to developing novel analytical formulations customized for an Air Turbo-Rocket engine and discusses the discovered correlation of nitrogen oxides production with the fuel-to-air ratio (FAR), the Mach number, and the Damköhler number (Da), the last being a nondimensional variable directly related to hydrogen/air combustion, considering the matching between the residence time and the ignition delay times. The most complete formulation allows for reduction in the prediction errors below 5%.

The Volume 9, published for JFFHMT Journal.