This manuscript introduces a piecewise linear decomposition method devoted to a class of fractional-order dynamical systems composed of piecewise linear (PWL) functions. Inspired by the Adomian decomposition method, the proposed technique computes an approximated solution of fractional-order PWL systems using only linear operators and specific constants vectors for each sub-domain of the PWL functions, with no need for the Adomian polynomials. The proposed decomposition method can be applied to fractional-order PWL systems composed of nth PWL functions, where each PWL function may have any number of affine segments. In particular, we demonstrate various examples of how to solve fractional-order systems with 1D 2-scroll, 4-scroll, and $4\times 4$-grid scroll chaotic attractors by applying the proposed approach. From the theoretical and implementation results, we found the proposed approach eliminates the unneeded terms, has a low computational cost, and permits a straightforward physical implementation of multi-scroll chaotic attractors on ARMs and FPGAs digital platforms.