Titanium dioxide (TiO₂) nanomaterials have been widely used in photocatalytic energy conversion and environmental remediation due to their advantages of low cost, chemical stability, and relatively high photo-activity. However, applications of TiO₂ have been restricted in the ultraviolet range because of the wide band gap. Broadening the light absorption of TiO₂ nanomaterials is an efficient way to improve the photocatalytic activity. Thus, black TiO₂ with extended light response range in the visible light and even near infrared light has been extensively exploited as efficient photocatalysts in the last decade. This review represents an attempt to conclude the recent developments in black TiO₂ nanomaterials synthesized by modified treatment, which presented different structure, morphological features, reduced band gap, and enhanced solar energy harvesting efficiency. Special emphasis has been given to the newly developed synthetic methods, porous black TiO₂, and the approaches for further improving the photocatalytic activity of black TiO₂. Various black TiO₂, doped black TiO₂, metal-loaded black TiO₂ and black TiO₂ heterojunction photocatalysts, and their photocatalytic applications and mechanisms in the field of energy and environment are summarized in this review, to provide useful insights and new ideas in the related field.

HCNs@HD-CoNi-LDH are fabricatedviaCd-based Prussian blue analog nanocubes twice sulfidation and epitaxial growth ZIF-67 etching into hollow defective CoNi-LDH strategies, which exhibit excellent sono-photocatalytic performance due to special bilayer porous hollow frameworks.