Sudden air pollution accidents (explosions, fires, leaks, etc.) in chemical industry parks may result in great harm to people’s lives, property, and the ecological environment. A gas tracking network can monitor hazardous gas diffusion using traceability technology combined with sensors distributed within the scope of a chemical industry park. Such systems can automatically locate the source of pollutants in a timely manner and notify relevant departments to take major hazards into their control. However, tracing the source of the leak in a large area is still a tough problem, especially within an urban area. In this paper, the diffusion of 79 potential leaking sources with consideration of different weather conditions and complex urban terrain is simulated by AERMOD. Only 61 sensors are used to monitor the gas concentration within such a large scale. A fully connected network trained with a hybrid strategy is proposed to trace the leaking source effectively and robustly. Our proposed model reaches a final classification accuracy of 99.14%.