In the pursuit of understanding the oxidation mechanisms of hydrogenated biodiesel fuels and elucidating the combustion behavior of biomass fuels when blended with diesel, this study presents a comprehensive investigation into the reaction mechanism of hydrogenated biodiesel–ethanol–diesel mixtures. We develop a comprehensive reaction mechanism encompassing 187 components and 735 reactions for hydrogenated biodiesel–ethanol–diesel mixtures. Through kinetics analysis under varied conditions, including 1.0 MPa pressure, an equivalence ratio of 1.0, and temperatures of 900 K and 1400 K, we explore the impact of cross-reactions and changing fuel blend ratios on low- and high-temperature oxidation. Our findings indicate that oleic and stearic acid methyl esters serve as better substitutes for representing hydrogenated biodiesel kinetics than methyl decanoate. At lower temperatures, increased hydrogenated biodiesel and ethanol content leads to reduced OH generation, impacting reactivity. Conversely, higher temperatures result in enhanced OH production with increased hydrogenated biodiesel and ethanol concentrations, promoting reactivity. A cross-reaction analysis reveals CH₂O as a prominent product, with the CH₂O→HCO→CO pathway playing a pivotal role. In summary, our research unveils the intricate oxidation mechanisms of hydrogenated biodiesel–ethanol–diesel mixtures, providing insights into their combustion characteristics and offering implications for optimizing fuel blends for cleaner and more efficient energy solutions.

The performance of centrifugal aviation fuel pumps can be crucial in determining aircraft efficiency and safety. Here, we delve into the intricate interplay between flight altitude and flow rate on pump performance. Employing the central composite design method, we characterized the relationship between these parameters and the pump’s head and efficiency. Our analysis, underpinned by response surface methodology, revealed distinct optimal operating conditions at 10,000 m and 12,000 m flight altitudes, pinpointed at flow rates of 1.1016 Q and 1.1222 Q, respectively. Moreover, the emergence and growth of cavitation regions with increasing flow rates underscore the challenges in pump operation. Significantly, we identify rotor–stator interactions as a dominant influence on pressure fluctuations, especially near the impeller exit. These findings not only elucidate the operational dynamics of aviation fuel pumps but also pave the way for advanced pump designs and optimizations.

This study explores the thermodynamic and kinetic properties of CeO₂ nano-fuels, with a particular focus on the influence of nanoparticle additives on the diffusion and thermal conductivity of C14-based fuel systems. Using molecular dynamics simulations and the COMPASS force field, we model the interactions between C14 molecules and CeO₂ nanoparticles, varying nanoparticle size and concentration. Our results reveal that the inclusion of CeO₂ nanoparticles leads to significant enhancements in both thermal conductivity (increasing by 9.8–23.6%) and diffusion coefficients (increasing by approximately 140%) within the 20 °C to 100 °C temperature range. These improvements are attributed to the interactions between nanoparticles and fuel molecules, which facilitate more efficient energy and mass transport. Notably, nanoparticles with smaller sizes (0.2 nm and 0.5 nm) exhibit more pronounced effects on both the thermodynamic and kinetic properties than larger nanoparticle analogs (20 nm and 50 nm). The study also highlights the temperature-dependent nature of these properties, demonstrating that nanoparticle additives enhance the fuel’s thermal stability and diffusion behavior, particularly at elevated temperatures. This work provides valuable insights into the optimization of nano-fuel systems, with potential applications in enhancing the performance and efficiency of diesel combustion and heat transfer processes.