Monodispersed hierarchical layered double hydroxide on silica spheres (LDH@SiO₂) with core–shell structures were developed for metalloporphyrin immobilization and the materials were used as oxidant catalysts of different substrates.

The synthesis of structured MgO is reported using feedstock starch (route I), citrus pectin (route II), and Aloe vera (route III) leaf, which are suitable for use as green fuels due to their abundance, low cost, and non-toxicity. The oxides formed showed high porosity and were evaluated as antimicrobial agents. The samples were characterized by energy-dispersive X-ray fluorescence (EDXRF), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The crystalline periclase monophase of the MgO was identified for all samples. The SEM analyses show that the sample morphology depends on the organic fuel used during the synthesis. The antibacterial activity of the MgO-St (starch), MgO-CP (citrus pectin), and MgO-Av (Aloe vera) oxides was evaluated against pathogens Staphylococcus aureus (ATCC 6538P) and Escherichia coli (ATCC 8739). Antifungal activity was also studied against Candida albicans (ATCC 64548). The studies were carried out using the qualitative agar disk diffusion method and quantitative minimum inhibitory concentration (MIC) tests. The MIC of each sample showed the same inhibitory concentration of 400 µg. mL⁻¹ for the studied microorganisms. The formation of inhibition zones and the MIC values in the antimicrobial analysis indicate the effective antimicrobial activity of the samples against the test microorganisms.

The present study described three synthesis routes using different natural polysaccharides as low-cost non-toxic fuels and complexing agents for obtaining MgO. Cassava starch, Aloe vera leaves (mainly acemannan) gel, and citric pectin powder were mixed with magnesium nitrate salt and calcined at 750 °C for 2 h. The samples were named according to the polysaccharide: cassava starch (MgO-St), citrus pectin (MgO-CP), and Aloe vera (MgO-Av). X-ray diffraction identified the formation of a monophasic periclase structure (FCC type) for the three samples. The N₂ adsorption/desorption isotherms (B.E.T. method) showed an important difference in textural properties, with a higher pore volume (V_max = 89.76 cc/g) and higher surface area (SA = 43.93 m²/g) obtained for MgO-St, followed by MgO-CP (V_max = 11.01 cc/g; SA = 7.01 m²/g) and MgO-Av (V_max = 6.44 cc/g; SA = 6.63 m²/g). These data were consistent with the porous appearance observed in SEM images. Porous solids are interesting as adsorbents for removing metallic and molecular ions from wastewater. The removal of copper ions from water was evaluated, and the experimental data at equilibrium were adjusted according to the Freundlich, Langmuir, and Temkin isotherms. According to the Langmuir model, the maximum adsorption capacity (q_max) was 6331.117, 5831.244, and 6726.623 mg·g⁻¹ for the adsorbents MgO-St, MgO-Av, and MgO-CP, respectively. The results of the adsorption isotherms indicated that the synthesized magnesium oxides could be used to decrease the amount of Cu²⁺ ions in wastewater.

This research aimed to investigate the effect of calcination temperature on the phase, morphological and optical properties of iron oxides: hematite (α‐Fe₂O₃), magnetite (Fe₃O₄) and goethite (α‐FeOOH), synthesised by co‐precipitation, aiming at their applications as pigments. The sample was characterised by thermogravimetric (TG) analysis, X‐ray diffractometry (XRD), scanning electron microscopy (SEM) and static light scattering (SLS) for structural analyses; colorimetry and ultraviolet–visible absorption spectroscopy to analyse optical properties. The TG and XRD analysis show that above 600°C, magnetite and goethite samples were transformed into hematite, showing excellent thermal stability. The magnetite showed smaller and more homogeneous particle sizes, as observed in SLS and SEM analysis. Colorimetric analyses revealed evident changes in colour and brightness, especially for goethite, which exhibited the highest total colour variation (60.1) at 800°C compared with the samples not calcinated. Furthermore, the tests highlighted that materials obtained through goethite synthesis are more promising as industrial pigments.