CuO-ZnO nanocomposites (NCs) were synthesized using an aqueous extract of Verbascum sinaiticum Benth. (GH) plant. X-ray diffraction (XRD), spectroscopic, and microscopic methods were used to explore the crystallinity, optical properties, morphology, and other features of the CuO-ZnO samples. Furthermore, catalytic performances were investigated for methylene blue (MB) degradation and 4-nitrophenol (4-NP) reduction. According to the results, CuO-ZnO NCs with 20 wt % CuO showed enhanced photocatalytic activity against MB dye with a 0.017 min^-1 rate constant compared to 0.0027 min^-1 for ZnO nanoparticles (NPs). Similarly, a ratio constant of 5.925 min^-1 g^-1 4-NP reductions was achieved with CuO-ZnO NCs. The results signified enhanced performance of CuO-ZnO NCs relative to ZnO NPs. The enhancement could be due to the synergy between ZnO and CuO, resulting in improved absorption of visible light and reduced electron-hole (e^-/h⁺) recombination rate. In addition, variations in the CuO content affected the performance of the CuO-ZnO NCs. Thus, the CuO-ZnO NCs prepared using V. sinaiticum Benth. extract could make the material a desirable catalyst for the elimination of organic pollutants.

Nanomaterial-based catalytic conversion of hazardous organic pollutants into benign substances is one of the green methods employed for wastewater treatment. This study demonstrates the fabrication of (rGO-ZnO)/CuO nanocomposites (NCs) via a microwave (MW)-assisted method for (photo)catalytic application. The crystal structure, optical, morphological, and electrochemical characteristics were examined using X-ray diffraction (XRD), spectroscopic, microscopic, and electrochemical techniques. The analysis indicated that rod-like (rGO-ZnO)/CuO NCs having a nanoscale diameter with enhanced light absorption and well-matched band positions between rGO-ZnO and CuO were formed. Furthermore, the catalytic reduction of 4-nitrophenol (4-NP) and photocatalytic degradation of methylene blue (MB) tests showed remarkable results with rate constants of 0.468 min⁻¹ for 4-NP reduction within 8 min and 0.02213 min⁻¹ for MB degradation within 105 min. Thus, the artful decoration of ZnO nanorods (NRs) with CuO into the (rGO-ZnO)/CuO NCs interface is an effective strategy for fabricating highly efficient photocatalysts.

Water splitting driven by renewable energy sources is considered a sustainable way of hydrogen production, an ideal fuel to overcome the energy issue and its environmental challenges. The rational design of electrocatalysts serves as a critical point to achieve efficient water splitting. Layered double hydroxides (LDHs) with two-dimensionally (2D) layered structures hold great potential in electrocatalysis owing to their ease of preparation, structural flexibility, and tenability. However, their application in catalysis is limited due to their low activity attributed to structural stacking with irrational electronic structures, and their sluggish mass transfers. To overcome this challenge, attempts have been made toward adjusting the morphological and electronic structure using appropriate design strategies. This review highlights the current progress made on design strategies of transition metal-based LDHs (TM-LDHs) and their application as novel catalysts for oxygen evolution reactions (OERs) in alkaline conditions. We describe various strategies employed to regulate the electronic structure and composition of TM-LDHs and we discuss their influence on OER performance. Finally, significant challenges and potential research directions are put forward to promote the possible future development of these novel TM-LDHs catalysts.

We outline the synthesis approaches of Ni-utNSs toward improvement in morphology, active structures, efficiency, and stability as well as their electrocatalytic mechanism in order to achieve clean H₂ production through overall water splitting.