Land imperviousness reflects settlement growth and urban sprawl. Grounded on a comparative approach, a set of multidimensional statistical techniques were adopted here to quantify the evolution of land imperviousness from Copernicus High-Resolution Layers (HRLs) in a representative case study of Southern Europe (Athens, Greece). A two-way data matrix reporting the percent share of the surface land exposed to different sealing levels (101 classes ranging continuously from 0% to 100%) in the total municipal area was computed for two years (2006 and 2018) individually for 115 municipalities in metropolitan Athens. This matrix represented the information base needed to derive place-specific urban footprints and a comprehensive (global) profile of land imperviousness. Results of a Detrended Correspondence Analysis (DCA) delineated a metropolitan structure still organized along the density gradient, moving from dense settlements in central locations with dominant land classes sealed for more than 90% of their surface area to completely pervious land (0%) typical of rural locations. While the density gradient became less steep between 2006 and 2018, it continued to aliment a socioeconomic polarization in urban and rural districts with distinctive profiles of land imperviousness. Intermediate locations had more mixed imperviousness profiles as a result of urban sprawl. Differential profiles reflect place-specific urban footprints with distinctive land take rates.