For three types of colloidal magnetic nanocrystals, we demonstrate that postsynthetic cation exchange enables tuning of the nanocrystal’s magnetic properties and achieving characteristics not obtainable by conventional synthetic routes. While the cation exchange procedure, performed in solution phase approach, was restricted so far to chalcogenide based semiconductor nanocrystals, here ferrite-based nanocrystals were subjected to a Fe2+ to Co2+ cation exchange procedure. This allows tracing of the compositional modifications by systematic and detailed magnetic characterization. In homogeneous magnetite nanocrystals and in gold/magnetite core shell nanocrystals the cation exchange increases the coercivity field, the remanence magnetization, as well as the superparamagnetic blocking temperature. For core/shell nanoheterostructures a selective doping of either the shell or predominantly of the core with Co2+ is demonstrated. By applying the cation exchange to FeO/CoFe2O4 core/shell nanocrystals the Neél temperature of the core material is increased and exchange-bias effects are enhanced so that vertical shifts of the hysteresis loops are obtained which are superior to those in any other system.
This work reports on the hysteresis behavior and an initial baseline drift of printed strain gauges embedded in organic coating layers on sheet steel that we recently introduced. We subsequently investigated the performance over an extended period of time, which revealed interesting and partially unexpected material properties of printed strain gauges made from silver and carbon. Both silver- and carbon-based strain gauges show a hysteresis behavior of the gauge factor and non-negligible nonlinear characteristics. Furthermore, the carbon-based sensors show a strong initial base line drift within the first 50–100 cycles. All three effects, namely hysteresis, nonlinear gauge factor and initial base line drift, are confirmed within their respective standard deviations.
1 September 2018 in Sensors and Actuators A: Physical