Molybdenum disulfide (MoS2) screen-printed working electrodes were developed for dopamine (DA) electrochemical sensing. MoS2 working electrodes were prepared from high viscosity screen-printable inks containing various concentrations and sizes of MoS2 particles and ethylcellulose binder. Rheological properties of MoS2 inks and their suitability for screen-printing were analyzed by viscosity curve, screen-printing simulation and oscillatory modulus. MoS2 inks were screen-printed onto conductive FTO (Fluorine-doped Tin Oxide) substrates. Optical microscopy and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDX) analysis were used to characterize the homogeneity, topography and thickness of the screen-printed MoS2 electrodes. The electrochemical performance was assessed through differential pulse voltammetry. Results showed an extensive linear detection of dopamine from 1 µM to 300 µM (R2 = 0.996, sensitivity of 5.00 × 10–8 A μM−1), with the best limit of detection being 246 nM. This work demonstrated the possibility of simple, low-cost and rapid preparation of high viscosity MoS2 ink and their use to produce screen-printed FTO/MoS2 electrodes for dopamine detection.
We present a rapid and low-temperature (70 °C) route for the preparation of crystalline TiO2 on Ti3C2Tx MXene surfaces using atmospheric pressure oxygen plasma. Reactive oxygen species from plasma break the MXene structure and form TiO2 nanoparticles.
The TiO2 electrode has a key role in dye sensitized solar cell (DSSC) technology in the charge generation and charge transportation. The properties of TiO2 layer affect resulting efficiency of DSSC and can be controlled by printing process and chemical composition of printing paste. TiO2 pastes with different compositions of TiO2 nanoparticles, ethanol, ethyl cellulose, water, acetic acid, α-terpineol were prepared and screen printed onto the glass substrate with fluorine doped tin oxide (FTO). The TiO2 pastes for screen printing were characterized by rheological measurements and screen printed TiO2 electrodes by atomic force microscopy and UV-Vis spectroscopy. The photocurrent - voltage characteristics and efficiencies of DSSC were evaluated and compared. All prepared TiO2 pastes were suitable for screen printing with ideal rheological characteristics. The highest efficiency 0.68 % and current density ISC = 1.21 mA/cm2 reached by the DSSC based on TiO2 electrode with thickness 1.5 μm, with amount of absorbed dye 1.1 × 10-8 mol/cm2 and without visible cracks and particles aggregation. This TiO2 electrode was prepared from the paste containing 5.4 wt. % of TiO2, 65.3 wt. % of ethanol, 1.8 wt. % of ethyl cellulose, 23 wt. % of H2O and 4.5 wt. % of CH3COOH.
Silver nanoparticles (AgNPs) have attracted tremendous attention in recent years due to their unique physicochemical properties, including pronounced surface plasmon resonance, tunable size, and amenability to functionalization. These attributes underpin the growing interest in AgNPs as SMART nanocarriers for targeted drug delivery and as active components in biosensing platforms. In this work, we discuss various synthesis strategies for AgNPs—ranging from conventional chemical methods to green approaches—and highlight their subsequent functionalization with anticancer drugs, notably doxorubicin (DOX). We also examine the potential of AgNPs in biosensor applications, emphasizing electrochemical and optical detection modalities capable of monitoring drug release, oxidative stress, and relevant biomarkers. Our experimental data support the conclusion that AgNPs can effectively improve therapeutic efficacy by exploiting tumor-specific conditions (e.g., lower pH) while also enhancing biosensor sensitivity via surface plasmon resonance and electrochemical signal amplification. We provide a thorough discussion of the results, including mechanistic aspects of reactive oxygen species (ROS) generation, drug release kinetics, and sensor performance metrics. Overall, AgNP-based nanocarriers emerge as a powerful platform to address current challenges in precision oncology and medical diagnostics.
1 December 2023 in Materials Science in Semiconductor Processing