Interconnected hollow-structured carbon was successfully prepared from a readily available bio-waste precursor (orange peel) by pyrolysis and chemical activation (using KOH), and demonstrated its potential as a high-performing electrode material for energy storage. The surface area and pore size of carbon were controlled by varying the precursor carbon to KOH mass ratio. The specific surface area significantly increased with the increasing amount of KOH, reaching a specific surface area of 2521 m²/g for a 1:3 mass ratio of precursor carbon/KOH. However, a 1:1 mass ratio of precursor carbon/KOH displayed the optimum charge storage capacitance of 407 F/g, owing to the ideal combination of micro- and mesopores and a higher degree of graphitization. The capacitive performance varied with the electrolyte employed. The orange-peel-derived electrode in KOH electrolyte displayed the maximum capacitance and optimum rate capability. The orange-peel-derived electrode maintained above 100% capacitance retention during 5000 cyclic tests and identical charge storage over different bending status. The fabricated supercapacitor device delivered high energy density (100.4 µWh/cm²) and power density (6.87 mW/cm²), along with improved performance at elevated temperatures. Our study demonstrates that bio-waste can be easily converted into a high-performance and efficient energy storage device by employing a carefully architected electrode–electrolyte system.

In the last several years, conventional Drug Delivery Systems (DDS) have evolved into DDS that are responsive to exogenous or endogenous stimuli. The objective of this work was to present a DDS that is responsive to an electric stimulus, in the form of bipolar electric pulses. The DDS structure is based on chitosan embedded with magnetic nanoparticles, and crosslinked with polyethylene glycol dimethacrylate to form microbeads. This DDS is loaded with vancomycin as the therapeutic agent of interest. Silver Inter-Digitated Electrodes (IDE) were printed on Polyimide substrates with a MEMS-based inkjet material deposition printer, and used to provide 100 Hz pulses of electric current to the DDS for 3 min. The results showed that the stimulated groups released ∼800% more vancomycin than the non-stimulated groups in the excitation duration, but followed a first-order elution profile otherwise. Another significance of our approach is that it does not need complicated or expensive fabrication processes, and can be customized according to the targeted implant site. The IDE system has also been modeled using COMSOL® to study the distributed electric fields and ion migration during the stimulus. This work demonstrates a novel and promising technique of providing stimulus to drug substrates for controllable drug delivery.