Owing to excellent high-temperature mechanical properties, i.e., high heat resistance, high strength, and high corrosion resistance, Ti alloys can be widely used as structural components, such as blades and wafers, in aero-engines. Due to the complex shapes, however, it is difficult to fabricate these components via traditional casting or plastic forming. It has been proved that additive manufacturing (AM) is an effective method of manufacturing such complex components. In this study, four main additive manufacturing processes for Ti alloy components were reviewed, including laser powder bed melting (SLM), electron beam powder bed melting (EBM), wire arc additive manufacturing (WAAM), and cold spraying additive manufacturing (CSAM). Meanwhile, the technological process and mechanical properties at high temperature were summarized. It is proposed that the additive manufacturing of titanium alloys follows a progressive path comprising four key developmental stages and research directions: investigating printing mechanisms, optimizing process parameters, in situ addition of trace elements, and layered material design. It is crucial to consider the development stage of each specific additive manufacturing process in order to select appropriate research directions. Moreover, the corresponding post-treatment was also analyzed to tailor the microstructure and high-temperature mechanical properties of AMed Ti alloys. Thereafter, to improve the mechanical properties of the product, it is necessary to match the post-treatment method with an appropriate additive manufacturing process. The additive manufacturing and the following post-treatment are expected to gradually meet the high-temperature mechanical requirements of all kinds of high-temperature structural components of Ti alloys.
In this study, TA15 titanium alloys were successfully prepared using selective laser melting (SLM). The results show that the microstructure of each TA15 specimen is composed of a large number of acicular α’ martensite crystals accompanied by a lot of dislocations and twin structures in the martensite due to non-equilibrium heating and cooling via SLM. After solution treatment and aging treatment, the martensite structure is successfully transformed into a typical duplex structure and an equiaxial structure. When there is an increase in the solution temperature, the size of the equiaxed primary α phase and the elongation of the specimen gradually increases, while the thickness of the layered secondary α phase and the tensile strength of the specimen decreases accordingly. After solution treatment at 1000 °C, the specimens show the best comprehensive mechanical properties, i.e., a high-temperature tensile strength of 715 MPa and a corresponding elongation of 24.5%. Subsequently, an appropriate solution–aging treatment is proposed to improve the high-temperature mechanical properties of SLMed TA15 titanium alloys in aerospace.
Due to the rare earth supply shortage, ThMn12-type RFe12-based (R is the rare earth element) magnets with lean rare earth content are gaining more concern. Most ThMn12-type RFe12 structures are thermodynamically metastable and require doping of the stabilizing element Ti. However, the Ti-doping effects on the hard magnetic properties of RFe11Ti have not been thoroughly investigated. Herein, based on density functional theory calculations, we report the Ti-doping effects on the phase stability, intrinsic hard magnetic properties and electronic structures of RFe11Ti (R = La, Ce, Pr, Nd, Sm, Y, Zr). Our results indicate that Ti-doping not only increases their phase stability, but also enhances the magnetic hardness of ground-state RFe12 phases. Particularly, it leads to the transition of CeFe11Ti and PrFe11Ti from easy-plane to easy-axis anisotropy. Charge density distributions demonstrate that Ti-doping breaks the original symmetry of the R-site crystal field, which alters the magnetic anisotropy of RFe11Ti. Projected densities of states reveal that the addition of Ti results in the shift of occupied and unoccupied f-electron energy levels of rare earth elements, affecting their magnetic exchange. This study provides an insight into regulating the hard magnetic properties of RFe12-based magnets by Ti-doping.
Enhancing grain orientation along the crystal axis in AlNiCo alloys is crucial for developing high-performance permanent magnets. Traditional directional solidification, known as the “cold plate-hot mold” method, is constrained by a low thermal gradient, leading to inadequate microstructural uniformity and crystallographic alignment, which impedes the optimization of magnetic properties. In this study, we employed a high-speed solidification process with an enhanced cooling gradient to fabricate AlNiCo magnets at various withdrawal rates. The variation in drawing rate influenced grain orientation within the alloy, thereby altering the degree of alignment of the ferromagnetic α1 phase following subsequent heat treatment, which ultimately affected the magnetic properties. The optimal magnetic performance was attained at a withdrawal rate of 50 μm/s, where the sample exhibited the most favorable oriented microstructure, with a remanence (Br) of 10.62 kGs, intrinsic coercivity (Hcj) of 1.794 kOe, and a maximum energy product (BH)max of 10.93 MGOe. Moreover, magnets at different positions exhibit excellent consistency in magnetic properties, enhancing the material utilization efficiency. This research provides valuable process parameters and a foundational basis for developing high-performance AlNiCo alloys.
Rare-earth permanent magnet synchronous motors (PMSMs) are commonly used in new energy vehicles, wind power generation, and other relevant fields due to their advantages of small size and high power density. The operation of this type of motor depends on a rare-earth permanent magnet. However, the compatibility between the permanent magnet and the motor under different motor operating conditions is unclear, which is unfavorable for the subsequent selection of motor magnets. In this study, the effects of the permanent magnet on motor performance in different operational environments were analyzed. Three different magnets, namely, N-52M, N-48SH, and SmCo-28H, were selected. Two types of operational conditions were selected: the motor temperature and input current. The load torque, the magnet’s demagnetization behavior, and the magnet’s cost-effectiveness were discussed. The results indicate that the N-52M magnet was suitable for a low temperature and low input current due to its high remanence. However, the SmCo-28H magnet should be used at high temperatures and input currents due to its superior anti-demagnetization properties. The results obtained in this study will enable comparison of the effects of different permanent magnet materials on the motor, thereby guiding the subsequent design of PMSMs.