Layer-structured MoS2 is regarded as a promising anode material for potassium ion batteries. Herein, MoS2 nanosheets on N, P-codoping reduced graphene oxide (MoS2/N, P-rGO) have been successfully prepared via a facile two-step synthesis, where few-layered MoS2 nanosheets are chemically bonded onto the surface of N, P-rGO. As an anode material, MoS2/N, P-rGO exhibits a high specific capacity (462.7 mAh·g−1 at 100 mA·g−1 over 200 cycles), outstanding rate capability (224.9 mAh·g−1 at 20 A·g−1), and excellent cycle life (236.6 mAh·g−1 at 2 A·g−1 after 7,000 cycles), much better than those of MoS2 and MoS2/rGO. These advanced performances outperform most of the reported anode materials for potassium ion batteries to date. Meanwhile, the K-storage reactions of MoS2/N, P-rGO have been disclosed through in-situ and ex-situ characterizations. The kinetics analysis confirms that K-storage of MoS2/N, P-rGO is predominant by pseudo-capacitance.
A bio-nanocluster (Fe3O4@bacteria) was prepared by simply mixture using the bacterial suspension and Fe3O4 nanoclusters to remove Congo red (CR) contamination from water resources. The bio-nanocluster was characterized by SEM, TEM and XPS. Adsorption efficiency, adsorption process and adsorption mechanism were comprehensively investigated. The maximum adsorption capacity (Qm) of CR dye onto the Fe3O4@bacteria peaked at 320.1 mg/g, which was 2.88 times that of Fe3O4 under the same condition. Based on the equilibrium and kinetic studies, the Langmuir isotherm theory and pseudo-first-order model is appropriate to describe the adsorption process. The adsorption of CR is spontaneous and exothermic according to the thermodynamics parameters (ΔGθ, ΔHθ and ΔSθ). The adsorption force dominated the Van der Waals force, biofloculation and chemisorption. The Fe3O4@bacteria could be applied potentially as an absorbent with high efficiency and environmentally friendly remediation of dyeing wastewater.