Silica precipitation from high-enthalpy, depressurized supercritical fluids is investigated to determine the best method for accessing the scaling potential as a function of time, position and fluid composition. The most relevant knowledge application is for geothermal sources where the wells are drilled closed to magma and the temperature gradients in the rock are very high. The power potential per well for such a system is large compared to conventional geothermal power production, but several knowledge gaps, among them mineral precipitation from produced fluids, limit commercial use. For the high-enthalpy supercritical well fluid used as a base case in this review, conventional methods for reducing the silica content before it enters a turbine limit the power output. Knowledge of the particle-number density, size and time scales of growth in different depressurization scenarios, along with the silica solubility, kinetics and morphology, is essential to handle deposits and avoid scaling in inconvenient parts of the power plant. Experimental data on the precipitation of silica from highly supersaturated superheated steam are scarce, and it is known that the kinetics of precipitation in steam differ from those of liquid water. We argue that to quantify the number of solids in the depressurized supercritical fluid and superheated steam, dividing the process into three separate but dependable mathematical steps is a reliable approach: (1) the nucleation of nanocolloids, (2) growth by agglomeration, and (3) deposition onto a surface.

This article presents the results of an experimental investigation of silica deposition from depressurized supercritical steam. The case investigated is relevant for supercritical geothermal reservoirs with high temperature and pressure, where silica content is significant and deposition occurs rapidly upon depressurization. The purpose of the presented experiments is to accurately measure the deposited mass in two different areas in a flow tube and mathematically relate the measurement to particle formation behavior. In addition, SEM analysis permits valuable insight into the morphology of the scale formed under these conditions. The measured deposition is caused by silica solids formed when depressurizing supercritical fluids from around 350 bar and 500 °C by an isenthalpic valve to a state of superheated steam and pressures ranging from 60 to 150 bar. A test rig was designed, fabricated, and used for this purpose. The deposition mechanisms differ from silica particle formation in the water phase and the limited experimental research for the investigated conditions makes the gathered data highly interesting. The measured results are compared to validated models for deposition in straight pipes. The knowledge obtained on silica solidification and deposition can be used to optimize steam treatment of high-temperature pressurized geothermal sources for maximum power utilization by aiding in the development of advanced prediction tools for scaling and mineral extraction.

A model that can be used to quantify silica deposition from superheated depressurized steam is developed. Classical nucleation theory, agglomeration and deposition onto a wall are combined in a numerical model that calculates the concentration profile, the particle size distribution and the deposition in a flow through a pipeline after a sudden increase in supersaturation. The work presented here is an important step in understanding the mechanisms governing precipitation from supercritical and superheated steam as produced by deep geothermal wells drilled in magmatic areas. The power potential in such systems can be significantly higher than for conventional systems if utilized efficiently. The presented results can be applied to improve industrial designs and decrease energy costs. The model predicts the amount of precipitation along a pipe at various supersaturations, and the resulting deposition velocity in a straight pipe correlates fairly well with recent experimental results. There is a high number of nanocolloids formed close to the pressure reduction position, where deposition is at its maximum. Downstream, larger agglomerates develop, and deposition decreases as the number of particles and the overall concentration decreases. The local maximum deposition rate increases with increasing supersaturation. The calculations show that deposition mechanisms are as important as the chemical process of solidification when estimating where and how most material will be deposited. The rapid formation and deposition of solids predicted indicate that depressurization along with solid capture could be used to rid fluid of silica.

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