Early treatments of flames as gasdynamic discontinuities in a fluid flow are based on several hypotheses and/or on phenomenological assumptions. The simplest and earliest of such analyses, by Landau and by Darrieus prescribed the flame speed to be constant. Thus, in their analysis they ignored the structure of the flame, i.e. the details of chemical reactions, and transport processes. Employing this model to study the stability of a plane flame, they concluded that plane flames are unconditionally unstable. Yet plane flames are observed in the laboratory. To overcome this difficulty, others have attempted to improve on this model, generally through phenomenological assumptions to replace the assumption of constant velocity. In the present work we take flame structure into account and derive an equation for the propagation of the discontinuity surface for arbitrary flame shapes in general fluid flows. The structure of the flame is considered to consist of a boundary layer in which the chemical reactions occur, located inside another boundary layer in which transport processes dominate. We employ the method of matched asymptotic expansions to obtain an equation for the evolution of the shape and location of the flame front. Matching the boundary-layer solutions to the outer gasdynamic flow, we derive the appropriate jump conditions across the front. We also derive an equation for the vorticity produced in the flame, and briefly discuss the stability of a plane flame, obtaining corrections to the formula of Landau and Darrieus.

The focus of this article is on intrinsic combustion instabilities in both premixed and nonpremixed systems, identifying, in particular, the roles of differential and preferential diffusion, thermal expansion, and heat losses. For premixed flames, the hydrodynamic instability resulting from thermal expansion plays a central role and is particularly dominant in large-scale flames. It is responsible for the formation of sharp folds and creases in the flame front and for the wrinkling observed over the surface of expanding flames. In contrast, instabilities in diffusion flames, which give rise to cellular and oscillating flames, are mainly driven by diffusive-thermal effects, with thermal expansion playing a secondary role. The discussion also includes instabilities of edge-flames in unmixed reactants, which possess stability characteristics of both premixed and diffusion flames, but with a distinct mode of instability.

Based on a hydrodynamic length, which is typically larger than the nominal flame thickness, a premixed flame can be viewed as a surface of density discontinuity, advected and distorted by the flow. The velocities and the pressure suffer abrupt changes across the flame front that consist of Rankine–Hugoniot jump conditions, to leading order, with corrections of the order of the flame thickness that account for transverse fluxes and accumulation. To complete the formulation, expressions for the flame temperature and propagation speed, which vary along the flame as a result of local non-uniformities in the flow field and of flame front curvature, are derived. Unlike previous studies that assumed a mixture consisting of a single deficient reactant, the present study uses a two-reactant scheme and thus considers mixtures whose compositions vary from lean to rich conditions. Furthermore, non-unity and general reaction orders are considered in an attempt to mimic a wider range of reaction mechanisms and, to better represent actual experimental conditions, all transport coefficients are allowed to depend arbitrarily on temperature. The present model, expressed in a coordinate-free form, is valid for flames of arbitrary shape propagating in general fluid flows, either laminar or turbulent.