Crop straw burning frequently occurs in Central China, where agriculture is highly productive. We carried out a two-month observation on straw burning in Hubei Province from September 1 to October 31, 2015 to track the variations of air pollutants and comprehensively quantify their influence on regional air quality. Results showed that the concentration of suspended particles (particles smaller than 2.5 or 10 µm, i.e., PM2.5/PM10) and gas pollutants including ozone (O3), sulfur dioxide (SO2), nitrogen dioxide (NO2), and carbon monoxide (CO) was significantly enhanced with the increasing number of fire spots. The average daily concentrations of PM10, PM2.5 and O3 during the intensive burning period (from October 12 to 25) exceeded the daily limits published by the World Health Organization (WHO) by 101.8, 72.7 and 59.1 μg/m3, respectively. In the hourly distribution of pollutant concentration, PM10, PM2.5, O3, SO2, NO2 and CO were 63.49%, 46.29%, 65.56%, 64.40%, 48.57% and 13.49% higher during burning periods than during non-burning periods. Statistical results based on the air quality index (AQI) indicated that biomass burning was the key factor for the deterioration of local air quality, with a contribution ratio exceeding 41%. Additionally, the pollutants were more spatially homogeneous during the burning period than during the non-burning period. Straw burning not only worsened the local air quality but also raised the pollution level of surrounding regions due to the transport of air mass.
In order to study the pollution characteristics, sources, and health risks of heavy metals in urban atmospheric PM2.5, samples were collected in Huangshi City from June 2021 to May 2022. The contents of 16 kinds of metal elements were analyzed by XRF, and the pollution degree and sources of elements were analyzed by the enrichment factor method, correlation analysis, and cluster analysis. The health risk of heavy metal elements was evaluated by the USEPA health risk assessment model. The results of enrichment factor analysis show that the metal elements carried by PM2.5 were affected by human emissions except for Ti. Heavy metals mainly come from industrial sources, motor vehicle sources, mixed combustion sources, and dust sources, according to correlation analysis and cluster analysis. Mn had a non-carcinogenic risk to children, and the non-carcinogenic risk of other elements to the human body was generally acceptable. The carcinogenic risks of Cr, As, Cd, and Co exceeded the acceptable carcinogenic risk threshold (10−6 ~10−4), and there were potential carcinogenic risks.