Lignocellulosic fibers extracted from plants are considered an interesting raw material for environmentally friendly products with multiple applications. This work investigated the feasibility of using hemp- and flax-based materials in the form of felts as biosorbents for the removal of metals present in aqueous solutions. Biosorption of Al, Cd, Co, Cu, Mn, Ni and Zn from a single solution by the two lignocellulosic-based felts was examined using a batch mode. The parameters studied were initial metal concentration, adsorbent dosage, contact time, and pH. In controlled conditions, the results showed that: (i) the flax-based felt had higher biosorption capacities with respect to the metals studied than the hemp-based felt; (ii) the highest removal efficiency was always obtained for Cu ions, and the following order of Cu > Cd > Zn > Ni > Co > Al > Mn was found for both examined biosorbents; (iii) the process was rapid and 10 min were sufficient to attain the equilibrium; (iv) the efficiency improved with the increase of the adsorbent dosage; and (v) the biosorption capacities were independent of pH between 4 and 6. Based on the obtained results, it can be considered that plant-based felts are new, efficient materials for metal removal.

FINEAU (2021–2024) is a trans-disciplinary research project involving French, Serbian, Italian, Portuguese and Romanian colleagues, a French agricultural cooperative and two surface-treatment industries, intending to propose chènevotte, a co-product of the hemp industry, as an adsorbent for the removal of pollutants from polycontaminated wastewater. The first objective of FINEAU was to prepare and characterize chènevotte-based materials. In this study, the impact of water washing and treatments (KOH, Na₂CO₃ and H₃PO₄) on the composition and structure of chènevotte (also called hemp shives) was evaluated using chemical analysis, X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, X-ray computed nanotomography (nano-CT), attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy, solid state NMR spectroscopy and thermogravimetric analysis. The results showed that all these techniques are complementary and useful to characterize the structure and morphology of the samples. Before any chemical treatment, the presence of impurities with a compact unfibrillated structure on the surfaces of chènevotte samples was found. Data indicated an increase in the crystallinity index and significant changes in the chemical composition of each sample after treatment as well as in surface morphology and roughness. The most significant changes were observed in alkaline-treated samples, especially those treated with KOH.

Using a water-insoluble β-cyclodextrin-epichlorohydrin copolymer (β-EPI) as an adsorbent to remove carbamazepine (CBZ), an anti-epileptic drug often found both in hospital and urban wastewater, has been validated. The effect of several physicochemical parameters on CBZ retention onto β-EPI, such as contact time, adsorbent dosage, CBZ initial concentration, pH, salts, and temperature, was assessed. The adsorption process occurs in a very short time, less than 20 min, and depends on CBZ concentration and β-EPI amount used. Changes in pH and salt presence, regardless of the type of cation or anion used, do not significantly affect the system’s efficiency. Desorption experiments were also performed, and methanol has proven to be the best CBZ extraction medium; it was also found that the polymer can be recovered and reused for at least five cycles, which makes it cheap and environmentally friendly. Advanced oxidation processes were also tested for CBZ removal by synthesizing a β-EPI polymer bearing titanium dioxide for adsorption and consecutive photocatalytic degradation of the retained pollutant directly onto the material; the effect of TiO₂ amount in the polymer on CBZ oxidation was evaluated. These experiments highlighted the system’s effectiveness, and it was also observed that the H₂O₂ presence in the solution enhanced the CBZ photodegradation.

This article describes the performance of hemp shives, a co-product of the hemp industry, when used as an adsorbent to recover copper present in aqueous solutions by a batch method. Two materials provided by an industrial partner, namely water-washed hemp shives (SHI-W) and Na₂CO₃-activated shives (SHI-C), were studied. Two important variables in the water treatment industry, i.e., pH and ionic strength of the solution, were studied to evaluate their impact on the purification performance of the materials. The results obtained clearly indicated that the performance in terms of Cu removal obtained from the SHI-C material was significantly higher than that obtained with SHI-W, mainly due to the structural and chemical modifications after carbonate treatment. For each dose of this adsorbent, a percentage of recovery between 90 and 100% was achieved, independently of the pH value in the range 3–5. In the case of SHI-W, the highest values were between 60 and 75% and were both dependent on the pH and the dose used. SHI-C was also able to selectively remove 70% of copper in the presence of NaCl 1 M. The analysis of the isotherms indicated the presence of a complex adsorption mechanism that cannot be described by only one isotherm model.

This study describes the valorization of a pine wood by-product (Pinus pinaster) in the form of individualized fibers to a complex copper or more broadly metals present in an aqueous solution using a batch process. The adsorption results show that pine fibres activated by sodium carbonate are effective in recovering copper ions from monocontaminated or polycontaminated solutions of varying concentrations in a few minutes. One gram of material captures 2.5 mg of copper present in 100 mL of solution at pH 5 in less than 10 min. The results are perfectly reproducible and independent of pH between 3 and 5. The presence of the Na⁺ cation at concentrations of 0.1 M has no impact on material performance, unlike that of Ca²⁺ ions, which competes with Cu²⁺ ions for active sites. The adsorption process can be considered as rapid, as most of the copper is adsorbed within the first 10 min of exposure. Investigation of modeling possibilities shows some limitations. Indeed, the Weber and Morris and Elovich models show poor possibilities to describe all the kinetic data for copper adsorption on fibres. This may prove that the mechanism is far more complex than simple physisorption, chemisorption and/or diffusion. Complexation by wood fibers can be extended to solutions containing several types of metals. The results of this study show that the field of selective metal recovery could be a new way of valorizing by-products from the wood industry.