Getting Packed: If one neglects the role of specific interactions, the packing of similar-shaped objects will depend only on the particular shape of the object.
Damasceno
et al. (p. 453 ; see the Perspective by de Graaf and Manna ) present computer simulations of the behavior of different types of polyhedra with simple and complex shapes that are packed under thermal equilibrium into various structures, from crystals to amorphous materials through liquid crystals. Despite the wide variety of starting shapes, the packing behavior could be quantitatively described using just two criteria; one for the particle shape as a function of its volume and surface area, and one for the number of nearest neighbors.
We study photonic band gap formation in two-dimensional high-refractive-index disordered materials where the dielectric structure is derived from packing disks in real and reciprocal space. Numerical calculations of the photonic density of states demonstrate the presence of a band gap for all polarizations in both cases. We find that the band gap width is controlled by the increase in positional correlation inducing short-range order and hyperuniformity concurrently. Our findings suggest that the optimization of short-range order, in particular the tailoring of Bragg scattering at the isotropic Brillouin zone, are of key importance for designing disordered PBG materials.
7 November 2013 in Angewandte Chemie International Edition