This work presents a selective overview of natural fogs in terms of fog types, forms and states of occurrence, physical, micro-physical, chemical and dynamic properties, basic characterizing parameters, etc. In focus are related achievements and contributions reported mainly during the last decade and a half, as a result of both laboratory studies and field observations. Processes of homogeneous and heterogeneous nucleation are analyzed in the aspects of condensation, nuclei diversity and specifics, as related to the activation, growth and deposition of fog droplets. The effect is highlighted of the water vapor’s partial pressure on the surface tension of the liquid water–air interface and the freezing point of the water droplets. Some problems and aspects of fog modeling, parameterization, and forecasting are outlined and discussed on the examples of newly developed relevant 1D/3D theoretical models. Important issues of fog impacts on the air quality, ecosystems, water basins, societal life, and human health are also addressed and discussed, particularly in cases of anthropogenically modified (chemical, radioactive, etc.) fogs. In view of reducing the possible negative effects of fogs, conclusions are drawn concerning the new demands and challenges to fog characterization imposed by the changing natural and social environment and the needs for new data on and approaches to more adequate observations of fog-related events.

Emissions of immense amounts of desert dust into the atmosphere, spreading over vast geographical areas, are in direct feedback relation with ongoing global climate changes. An extreme large-scale Saharan dust episode occurred over Mediterranean and Europe in April 2019, driven by a dynamic blocking synoptic pattern (omega block) creating conditions for a powerful northeastward circulation of air masses rich in dust and moisture. Here, we study and characterize the effects of related dust intrusion over Sofia, Bulgaria, using lidar remote sensing combined with in situ measurements, satellite imagery, and modeling data. Optical and microphysical parameters of the desert aerosols were obtained and vertically profiled, namely, backscatter coefficients and backscatter-related Ångström exponents, as well as statistical distributions of the latter as qualitative analogs of the actual particle size distributions. Dynamical and topological features of the dust-dominated aerosol layers were determined. Height profiles of the aerosol/dust mass concentration were obtained by synergistic combining and calibrating lidar and in situ data. The comparison of the retrieved mass concentration profiles with the dust modeling ones shows a satisfactory compliance. The local meteorological conditions and the aerosol composition and structure of the troposphere above Sofia during the dust event were seriously affected by the desert air masses.

The wintertime outbreaks of Saharan dust, increasing in intensity and frequency over the last decade, have become an important component of the global dust cycle and a challenging issue in elucidating its feedback to the ongoing climate change. For their adequate monitoring and characterization, systematic multi-instrument observations and multi-aspect analyses of the distribution and properties of desert aerosols are required, covering the full duration of dust events. In this paper, we present observations of Saharan dust in the atmosphere above Sofia, Bulgaria, during a strong dust episode over the whole of Europe in February 2021, conditioned by a persistent blocking weather pattern over the Mediterranean basin, providing clear skies and constant measurement conditions. This study was accomplished using different remote sensing (lidar, satellite, and radiometric), in situ (particle analyzing), and modeling/forecasting methods and resources, using real measurements and data (re)analysis. A wide range of columnar and range/time-resolved optical, microphysical, physical, topological, and dynamical characteristics of the detected aerosols dominated by desert dust are obtained and profiled with increased accuracy and reliability by combining the applied approaches and instruments in terms of complementarity, calibration, and normalization. Vertical profiles of the aerosol/dust total and mode volume concentrations are presented and analyzed using the LIRIC-2 inversion code joining lidar and sun-photometer data. The results show that interactive combining and use of various relevant approaches, instruments, and data have a significant synergistic effect and potential for verifying and improving theoretical models aimed at complete aerosol/dust characterization.

Massive wildfires release enormous amounts of biomass-burning (BB) aerosols into the atmosphere, which might have a major impact on its thermal and radiative budget, as well as the environment and human health. This work presents the results of a study and characterization of a long-range transport episode of smoke aerosols from Canadian forest fires towards the entirety of Europe, as observed over Sofia, Bulgaria, in early October 2023. This study makes use of data from combined lidar, ceilometer, and sun-photometer measurements, supported by model and forecast data, meteorological radiosonde profiling, and (re)analyses, together with tracking and mapping of the aerosol air transport. A distinctive feature of the considered episode over Europe is the downward movement of the air masses, entraining smoke aerosols from the continental mid-troposphere down to the near-surface layers. The driving mechanism of the long-range transport of BB aerosols and their spread over Europe is revealed. Optical parameters of the registered aerosols are determined and vertically profiled with a high range resolution by lidar data analysis. A wide set of columnar optical and microphysical aerosol characteristics is also provided by sun-photometer measurements. The results show a dominance of relatively fine modes of dry smoke particles in the submicron size range, with a predominantly low degree of non-sphericity, indicating minimal up-size aging during the BB aerosol transport from Canada to the Sofia region. The average daily aerosol radiative forcing is determined by sun-photometer measurements and briefly discussed.

A tunable pulsed Ti: Sapphire laser was used to determine low concentrations using intracavity absorption spectroscopy with temporal resolution. The dependence of the laser-pulse evolution time on the absorbance of a sample introduced in the cavity (solution of 3,3-diethylthiatricarbocyanine iodide in dimethylsulphoxide) was studied theoretically and experimentally. The minimal experimentally measured absorbance was 8×10⁻⁴. The possibility was shown of using a Ti:S laser to detect absorbance of 10⁻⁵ via a temporal technique.