The effect of cluster formation in a fullerene mixture C60/70 (D5h-C70 — 95 mass percent and Ih-C60 — 5 mass percent) solution in toluene on the electronic properties and the infrared absorption spectra during long-term (60 days) storage under isotermic conditions is studied. The features of the structure of (C60/70)N clusters have been studied using high-resolution transmission electron microscopy and a fractal mechanism is proposed for the formation of large (~291.4 nm) stable clusters, which may contain up to ~19698 molecules of C70 and ~1036 molecules of C60. The precise values of the nonlinear optical susceptibility χ(3)xyyx (ω) of the C60/70 solutions for different laser beam polarizations (in the range of ellipticities θ = 0.1 − 0.8) are determined. The physical mechanisms of the laser-induced optical activity of a C60/70 solution in toluene are discussed.
The problems of how to optimize the geometric parameters of the paraboloid-cylinder-receiver (PC-R) system of thermal power plants are examined. The optimal opening angles of the...
Semiconductor nanowhiskers, particularly nanostructured whiskers based on zero-dimensional (0D) C70 fullerene, are being actively discussed due to the great potential of their application in modern electronics. For the first time, we proposed and implemented a method for the synthesis of nanostructured C70 fullerene whiskers based on the self-organization of C70 molecules during the thermal evaporation of C70 droplets on the substrate surface. We found that the onset of the synthesis of C70 nanowhiskers upon the evaporation of drops of a C70 solution in toluene on the substrate surface depends on the substrate temperature. We have provided experimental evidence that an increase in both the C70 concentration in the initial drop and the substrate temperature leads to an increase in the geometric dimensions of C70 nanowhiskers. The obtained results provide useful vision on the role of solute concentration and substrate temperature in the synthesis of one-dimensional materials.
The first results of experimental investigations concerning laser radiation generation with pumping by concentrated solar radiation flux at the Big Solar Furnace of Materials Science Institute of...
A numerical model of a linear Frensel reflector (LFR) with oriented facets is suggested. The concentrating performances of linear Frensel reflectors are determined by considering the errors of...