Controlling the indoor air (volatile organic compound) VOCs concentration plays an important role in creating a healthy and comfortable living environment. Comparing several VOCs purification measures, solid adsorption is found to be a promising air cleaning method for civil buildings, which have diverse VOCs pollutants. For solid adsorption technology, absorbance is the key to its air-cleaning performance. Compared with traditional adsorbent materials, (metal–organic frameworks) MOFs have excellent physical parameters and are promising adsorbent materials. In this paper, the synthesis and adsorption mechanisms underlying several metal–organic frameworks are summarized. The exploration and experiment measurements of VOCs adsorption performance according to the metal–organic frameworks are summarized. The exploration of these materials’ stability during air cleaning is reviewed. Finally, some application examples of metal–organic frameworks for VOCs adsorption are given. This literature review demonstrates that metal–organic frameworks can be promising adsorbents for indoor air cleaning. The green synthesis methods, stability, adsorption performance under low concentration and diverse VOCs conditions, and application methods for metal–organic frameworks should be further researched before their large-scale application.

The air source heat pump (ASHP) is developing rapidly and is widely used for space heating due to its potential for increasing energy efficiency and reducing greenhouse gas emissions. The choice of appropriate low global warming potential (GWP) alternative refrigerants is one of the challenges that ASHP systems face. Alternative refrigerants also affect the energy performance of these systems. Thus, it is essential to evaluate the performance of ASHP using environmentally friendly refrigerants to facilitate reasonable refrigerant selection. A theoretical model for simulating ASHP performance with different refrigerants is developed in this study. Experiments are conducted to validate the theoretical model. The simulation and the experimental results are found to be in good agreement. The ASHP performance indices, such as compression ratio (CR), discharging temperature (DT) and coefficients of performance (COP), are investigated using R22, R417A, R410A, R134a, R152a, R161 and R1234yf as working fluids. The results show that R152a has an average COP of 2.7% higher than R22, and R161 has an average COP of 1.4% higher than R22. R152a and R161 also have a higher CR but a lower DT than R22 under the same design conditions. In addition, R152a and R161 have ozone depletion potentials (ODP) of zero and extremely low GWPs; thus, they can be candidates to replace R22 in ASHP heating systems. This research provides a reference on refrigerant replacements for ASHP heating systems in North China.

In this study, MIL-101 (Cr) was synthesized and characterized in terms of its physical properties. The adsorption breakthrough curves for toluene were measured and compared to those of conventional adsorbents (i.e., silica gel and activated carbon) at typical indoor concentrations of toluene. The results show that MIL-101 (Cr) exhibits a 5–8 times higher adsorption capacity for toluene compared to silica gel at low concentrations. The adsorption isotherm of MIL-101 (Cr) for toluene conforms to the Langmuir model. Increasing temperature reduces the adsorption breakthrough time and saturation time, but it leads to a significant decrease in the adsorption capacity. During the breakthrough experiment, flow rate had little effect on adsorption capacity, but higher flow rates notably decreased the breakthrough and saturation times. The negative values of ΔG, ΔH, and ΔS indicate that the adsorption of toluene on MIL-101 (Cr) is a spontaneous and exothermic process. Compared to traditional adsorbents, MIL-101 (Cr) exhibits desirable performance in toluene adsorption in indoor environments. It shows significant potential for indoor air purification applications.