Supercritical carbon dioxide (sCO₂) can be mixed with dopants such as titanium tetrachloride (TiCl₄), hexafluoro-benzene (C₆F₆), and sulphur dioxide (SO₂) to raise the critical temperature of the working fluid, allowing it to condense at ambient temperatures in dry solar field locations. The resulting transcritical power cycles have lower compression work and higher thermal efficiency. This paper presents the aerodynamic flow path design of a utility-scale axial turbine operating with an 80–20% molar mix of CO₂ and SO₂. The preliminary design is obtained using a mean line turbine design method based on the Aungier loss model, which considers both mechanical and rotor dynamic criteria. Furthermore, steady-state 3D computational fluid dynamic (CFD) simulations are set up using the k-ω SST turbulence model, and blade shape optimisation is carried out to improve the preliminary design while maintaining acceptable stress levels. It was found that increasing the number of stages from 4 to 14 increased the total-to-total efficiency by 6.3% due to the higher blade aspect ratio, which reduced the influence of secondary flow losses, as well as the smaller tip diameter, which minimised the tip clearance losses. The final turbine design had a total-to-total efficiency of 92.9%, as predicted by the CFD results, with a maximum stress of less than 260 MPa and a mass flow rate within 1% of the intended cycle’s mass flow rate. Optimum aerodynamic performance was achieved with a 14-stage design where the hub radius and the flow path length are 310 mm and 1800 mm, respectively. Off-design analysis showed that the turbine could operate down to 88% of the design reduced mass flow rate with a total-to-total efficiency of 80%.

Recent studies suggest that CO2 mixtures can reduce the costs of concentrated solar power plants. Radial inflow turbines (RIT) are considered suitable for small to medium-sized CO2 power plants (100 kW to 10 MW) due to aerodynamic and cost factors. This paper quantifies the impact of CO2 doping on RIT design by comparing 1D mean-line designs and aerodynamic losses of pure CO2 RITs with three CO2 mixtures: titanium tetrachloride (TiCl4), sulfur dioxide (SO2), and hexafluorobenzene (C6F6). Results show that turbine designs share similar rotor shapes and velocity diagrams for all working fluids. However, factors like clearance-to-blade height ratio, turbine pressure ratio, and fluid viscosity cause differences in turbine efficiency. When normalized for these factors, differences in total-to-static efficiency become less than 0.1%. However, imposing rotational speed limits reveals greater differences in turbine designs and efficiencies. The imposition of rotational speed limits reduces total-to-static efficiency across all fluids, with a maximum 15% reduction in 0.1 MW CO2 compared to a 3% reduction in CO2/TiCl4 turbines of the same power. Among the studied mixtures, CO2/TiCl4 turbines achieve the highest efficiency, followed by CO2/C6F6 and CO2/SO2. For example, 100 kW turbines achieve total-to-static efficiencies of 80.0%, 77.4%, 78.1%, and 75.5% for CO2/TiCl4, CO2/C6F6, CO2/SO2, and pure CO2, respectively. In 10 MW turbines, efficiencies are 87.8%, 87.3%, 87.5%, and 87.2% in the same order.