The estimation of infiltration is a main issue in runoff simulation. The geometry of hillslopes (plan shape and profile curvature) may affect the responses, as well as infiltration over the hillslopes. In this study, the equations of TOPMODEL (a topography-based model) were applied to complex hillslopes to develop the complex TOPMODEL. This model was coupled with the SCS-CN (Soil Conservation Service Curve Number) model to examine the effects of geometry on infiltration and derive a saturation excess-based curve number (CN). The effects of plan shape and profile curvature upon the spatial distribution of CN and infiltration were studied. The results show that convergent hillslopes have 15.4% less infiltration and divergent hillslopes have 7.8% more infiltration than parallel ones. The infiltration over concave hillslopes is 13.5% lower and infiltration over convex hillslopes 5.8% higher than for straight ones. The degree of convergence/divergence has a greater effect on the CN compared to that of profile curvature.