This study introduces an innovative approach to enhancing the corrosion resistance and tribological performance of magnesium alloys by in situ growing zinc-aluminum layered double hydroxide (ZnAl-LDHs) with graphene oxide (GO) sealing. Traditional LDHs coatings exhibit limitations in corrosion protection due to their porous structure. This paper advances the LDHs coating technology by integrating GO, forming a composite LDHs/GO coating on magnesium alloys. The novel incorporation of GO provides a unique two-layered defense system against corrosion: the GO layer serves as a high-resistance barrier to corrosive agents, while the LDHs layer absorbs NO₃⁻ ions, offering a secondary protection. The coating’s properties were meticulously characterized using techniques such as scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier-transform infrared (FTIR) Raman spectroscopy, electrochemical assays, and friction-wear tests. Experimental findings reveal that the synergistic action between LDHs and GO results in significant improvements in corrosion resistance and friction reduction. Specifically, GO’s adherence to the LDHs coating’s pores and its ability to transfer into the friction layer during wear significantly enhances the coating’s integrity and stability. The successful in situ synthesis of LDHs /GO coatings opens new horizons for composite coatings, with potential implications across various industrial applications.

High-pressure steam pipes inevitably suffered from the reciprocal interaction of high pressure and temperature during a long-period service, causing deformation and cracking. However, only limited studies about abnormal bulging caused by condensed water have been carried out. To study the relationship between bulging and condensed water, bulging tee joints belonging to high-pressure steam pipes were investigated with a macro visual inspection, chemical composition analysis, and metallographic microscopy. According to the analysis of the bulging samples, pearlite spheroidization was found in the abnormal bulging tee joint. The ANSYS FLUENT modeling indicated that the tube wall of bulging tees was continuously subjected to alternating stress, causing the cyclic transformation of the liquid–gas phase inside the tee joint. The results indicate that the stress produced by a condensed water droplet ranges from 532.8 MPa to 59 MPa, continuously exerting pressure on the tube wall of the tee joint. When combined with the variation in the temperature field, the temperature of the severe bulging tee joint and slight bulging tee joint alternates. Further modeling illustrates that the stress generated by the impact of condensed water droplets on the high-temperature tee joints causes a ratcheting effect, which is identified as the main factor contributing to the bulging of the tee joint. Deterioration of the microstructure is considered a secondary mechanism.

This paper investigates the failure of a regulating valve stem in a petrochemical plant, which was mainly caused by vibration fatigue under small opening conditions. The fractured valve stem was analyzed using macroscopic analysis, chemical composition analysis, mechanical property analysis, metallographic analysis, fracture surface observation, and energy spectrum analysis. Additionally, fluid-structure interaction (FSI) modal analysis was used to investigate the failure of the regulating valve. The results indicate that the valve opening had a direct impact on the vibration of the valve body, which, when operated at small openings, led to fatigue fracture at the step of variable cross-section. The paper suggests a smooth transition treatment be performed at the variable cross-section of the valve stem to avoid stress concentration. Although this study is limited to a specific case, it provides valuable insights for the failure analysis of valves operating at small openings.

The pyrolysis furnace, a critical component in a pyrolysis unit, inevitably faces operational challenges during its use. This study investigates a case of pyrolysis furnace failure, particularly focusing on an occurrence at the 90° lug elbow and furnace tube weld. The failure, characterized by a comprehensive fracture of the furnace tube in the circumferential direction along the weld vicinity, transpired within a timeframe significantly shorter than one-third of the design life. To unravel the root cause, a series of experiments was conducted on a sample extracted from the failed tube. These experiments, comprising visual inspection, chemical composition analysis, metallographic examination, microstructure analysis, fracture scanning electron microscopy, and energy spectrum analysis, collectively aimed at a comprehensive understanding of the failure mechanisms. The results disclosed that the fracture between the lug elbow and the inlet pipe stemmed from the presence of porosity and inclusions in the butt weld. The initiation of cracks was traced to the pores and inclusions in the fusion line of the inner wall of the pyrolysis tube, extending to connect with the pores in the heat-affected zone on the side of the pyrolysis tube parent material. Subsequently, under the influence of high temperature and stress, the cracks propagated, crept, and expanded along the circumference of the pyrolysis tube parent material until the final fracture occurred. In light of these findings, practical recommendations are proposed to mitigate the risk of similar failures in the future.

Heat exchangers, as essential devices for facilitating heat transfer, have found a variety applications in various industries. However, the occurrence of corrosion-related failures in real-world scenarios remains a prevalent problem that can lead to catastrophic incidents. This paper investigates the problem of corrosion perforation on the outlet flange of a heat exchanger in a sour steam stripper from a petrochemical company. Failure analysis was performed using physical testing and chemical analysis, metallographic examination, microscopic observation, and energy spectrum analysis. Intergranular corrosion experiments and flow calculations were performed to verify the analysis. The results indicate that the main cause of the flange corrosion perforation was the formation of a highly concentrated NH₄HS aqueous solution during the cooling process of the NH₃, H₂S, and water vapor in the fluid passing through the heat exchanger, and the velocity was too high, which triggered alkali-sour water washout corrosion. To prevent the recurrence of similar corrosion perforations, recommendations for material and process optimization are proposed to effectively reduce the safety production risks in refinery units and provide valuable information for the safe long-term operation of a sour steam stripper.