The problem of recycling and storage of phosphogypsum is topical for many countries around the world, as it is associated with environmental problems of pollution of water bodies, land, and atmosphere. Therefore, this paper analyzes the directions of phosphogypsum recycling and possible alternatives to its use. The main disadvantages of the existing methods of phosphogypsum processing were identified and trends in this waste management were also considered. Through the VOSviewer programme, a visualization of cluster interconnections was carried out in research publications of various fields of phosphogypsum utilization. Five clusters were formed: a red cluster—phosphogypsum recycling in the construction industry; green cluster—radiation pollution problem of phosphogypsum and phosphate fertilizers; yellow cluster—monitoring migration of phosphogypsum components in the ecosystem, with the mobile forms of heavy metals and their inflow into aquifers from phosphogypsum dumps; blue cluster—use of phosphogypsum in agriculture as an ameliorant and a component of fertilizer; and a purple cluster—the impact of phosphogypsum on microorganisms, particularly in bioremediation processes. Under the proposed integrated biochemical approach, the use of various bioprocesses of phosphogypsum recovery from waste dumps and implementation of new biotechnological solutions for processing phosphorus raw materials are presented.

The migration of heavy metals and radionuclides is interrelated, and this study focusses on the interaction and complex influence of various toxicants. The rehabilitation of radioactively contaminated territories has a complex character and is based on scientifically supported measures to restore industrial, economic, and sociopsychological relations. We aim for the achievement of pre-emergency levels of hygienic norms of radioactive contamination of output products. This, in its sum, allows for further economic activity in these territories without restrictions on the basis of natural actions of autoremediation. Biosorption technologies based on bacterial biomass remain a promising direction for the remediation of soils contaminated with radionuclides and heavy metals that help immobilise and consolidate contaminants. A comprehensive understanding of the biosorption capacity of various preparations allows for the selection of more effective techniques for the elimination of contaminants, as well as the overcoming of differences between laboratory results and industrial use. Observation and monitoring make it possible to evaluate the migration process of heavy metals and radionuclides and identify regions with a disturbed balance of harmful substances. The promising direction of the soil application of phosphogypsum, a by-product of the chemical industry, in bioremediation processes is considered.

This paper focuses on the analysis of current cooperation trends in environmental protection research. A unified system of interrelations between research methods in the field of implementation of the bibliometric approach to the review of international cooperation in the field of environmental protection taking into account the consequences of the COVID-2019 pandemic was formed. To form a unified visualization of the analyzed bibliometric data, a special software product VOSViewer was used. Five clusters were defined: green—international cooperation for assessing risks to public health, in particular in the field of biosafety and the spread of social infections, with a focus on COVID-19, in 2019 and 2020; yellow—describes the related interaction between other clusters in the field of national and international mechanisms of cooperation in the regulation of greenhouse gas emissions and climate change; blue—brings together research areas in the field of economics of environmental management and control. The situation concerning the impact of the COVID-2019 pandemic is ambiguous, and it is crucial to recognize that this is a long-term period of impact, not only directly on public health but also due to economic and social constraints, as quarantine activities cause a chain of socio-economic crises. The problems of the environmental and economic spread of COVID-19 on various human activities and the environment require the development of this topic and the formation of a new cluster of interactions due to the wave dynamics of disease in the future. Broad cooperation and collaboration is proposed to address the challenges and accelerate sustainable development in Europe. A diagram of the main cooperation programs has been created, illustrating the overlap of the entire field, from basic research to the market. Further analytical studies will examine the effectiveness of cross-analysis using various scientometric databases to form an integrated approach to the new realities of quarantine activities.

This paper investigates the influence of a phosphogypsum dump on the surrounding environment (soil ecosystem) in the Sumy region (Ukraine). Analysis of the surrounding soils was performed to study the possible presence of compounds leaching from the dump. For physical chemical analysis of samples, X-ray fluorescence (XRF) analysis, X-ray diffraction (XRD) analysis, and Fourier transform infrared spectrophotometry (FTIR) were used. XRF analysis did not confirm the contamination of soils around the phosphogypsum dump, and the soil fluoride levels measured in this study were comparable to the average soil fluoride concentration of soils globally. The colonization of the surface of the phosphogypsum dump by living organisms after the reclamation process was also analyzed. Field research was carried out on the routes, which specify the boundaries of the contours of plant communities, for description of phytocenoses in the territory of the dump, where the pH value ranged from 2.5 to 5.3, depending on the age of phosphogypsum terraces. Annual and perennial herbaceous plants are dominant on the reclaimed dump slopes. On the third and fourth phosphogypsum terraces (20 and 25 years old, respectively), tree forms have begun to settle, represented mainly by Populus tgemula, Populus alba, Betula pendula, and Robinia pseudoacacia. The studied patterns of ecological groups of plants growing under natural change of species can be used for the complete reclamation of the dump.

The paper is focused on the research of biochemical treatment of sewage sludge and phosphogypsum under sulphate-reducing conditions with a phosphorus release process. The theoretical foundations of the work were based on the biochemical formalization using the principles of autocatalysis of natural systems. During the experimental research for the control of physicochemical parameters of the process spectroquantic, X-ray fluorescence analysis and other techniques were used. A schematic model of the dephosphatation process under anaerobic stabilization of sewage sludge and phosphogypsum was developed. The increase of phosphogypsum dosage had a close correlation with the release of phosphate ions. At the stimulating action of the phosphogypsum additive, a 2.5–5.0-fold increase in soluble phosphate concentration was observed. The rational dose of phosphogypsum was determined. Along with an increase the ratio of COD (Chemical Oxygen Demand)/phosphogypsum to 0.1, an increase in the phosphate ions in solution was observed. A further increase in the ratio of COD/phosphogypsum did not affect the concentration of phosphate ions in solution.