Crater size–frequency analyses have shown that the largest volcanic plains deposits on Mercury were emplaced around 3.7 Ga, as determined with recent model production function chronologies for impact crater formation on that planet. To test the hypothesis that all major smooth plains on Mercury were emplaced by about that time, we determined crater size–frequency distributions for the nine next‐largest deposits, which we interpret also as volcanic. Our crater density measurements are consistent with those of the largest areas of smooth plains on the planet. Model ages based on recent crater production rate estimates for Mercury imply that the main phase of plains volcanism on Mercury had ended by ~3.5 Ga, with only small‐scale volcanism enduring beyond that time. Cessation of widespread effusive volcanism is attributable to interior cooling and contraction of the innermost planet.

We have analyzed the Bouguer anomaly (BA) of ~1200 complex craters in the lunar highlands from Gravity Recovery and Interior Laboratory observations. The BA of these craters is generally negative, though positive BA values are observed, particularly for smaller craters. Crater BA values scale inversely with crater diameter, quantifying how larger impacts produce more extensive fracturing and dilatant bulking. The Bouguer anomaly of craters larger than km in diameter is independent of crater size, indicating that there is a limiting depth to impact‐generated porosity, presumably from pore collapse associated with either overburden pressure or viscous flow. Impact‐generated porosity of the bulk lunar crust is likely in a state of equilibrium for craters smaller than ~30 km in diameter, consistent with an ~8 km thick lunar megaregolith, whereas the gravity signature of larger craters is still preserved and provides new insight into the cratering record of even the oldest lunar surfaces.

The evolution and compositional structure of the lunar mantle has been extensively modeled but insufficiently constrained by observations. Here, we identify and characterize mantle materials exposed by the Moon's largest impact basin to better understand the composition, stratigraphy, and evolution of the upper mantle. The vast South Pole‐Aitken Basin (SPA) exhibits a broad, crescent‐shaped thorium and potassium distribution. These incompatible elements are predicted to be concentrated in the dregs of the lunar magma ocean during end‐stage crystallization. Through consideration of basin formation models convolved with subsequent geologic evolution, we demonstrate that the distribution and implied stratigraphy of Th‐ and K‐bearing materials across SPA are consistent with an upper mantle ejecta origin. The most pristine exposures of these materials are confined to northwest SPA and also exhibit elevated Ti and Fe (relative to the farside highlands) in association with a gabbronoritic mineralogy. This is consistent with late‐stage magma ocean assemblages predicted by petrologic models. In contrast, SPA impact melt derived from greater depths is associated with a low‐Ca pyroxene‐dominated assemblage. Together, these compositional patterns are evidence for a stratified ancient upper mantle. Importantly, the incompatible‐element‐enriched, ilmenite‐bearing ferroan gabbronoritic cumulates evidently had not participated in gravitational overturn at the time of SPA formation. Contrary to recent hypotheses invoking nearside sequestration of incompatible elements to explain hemispherical differences in crustal building and volcanic resurfacing, it follows that incompatible elements were globally distributed in the magma ocean at the time of SPA formation.

Gravity observations from the dual Gravity Recovery and Interior Laboratory (GRAIL) spacecraft have revealed more than 100 quasi‐circular mass anomalies, 26–300 km in diameter, on the lunar nearside. These anomalies are interpreted to be impact craters filled primarily by mare deposits, and their characteristics are consistent with those of impact structures that formed prior to, and during, intervals of flooding of feldspathic terrane by mare basalt lavas. We determine that mare deposits have an average density contrast of kg m⁻³ relative to the surrounding crust. The presence of a large population of volcanically buried craters with minimal topographic expression and diameters up to 300 km requires an average nearside mare thickness of at least 1.5 km and local lenses of mare basalt as thick as ~7 km.

The formation of the largest and most ancient lunar impact basin, South Pole–Aitken (SPA), was a defining event in the Moon’s evolution. Using numerical simulations, we show that widespread mantle heating from the SPA impact can catalyze the formation of the long-lived nearside-farside lunar asymmetry in incompatible elements and surface volcanic deposits, which has remained unexplained since its discovery in the Apollo era. The impact-induced heat drives hemisphere-scale mantle convection, which would sequester Th- and Ti-rich lunar magma ocean cumulates in the nearside hemisphere within a few hundred million years if they remain immediately beneath the lunar crust at the time of the SPA impact. A warm initial upper mantle facilitates generation of a pronounced compositional asymmetry consistent with the observed lunar asymmetry.

While recent analyses of lunar samples indicate the Moon had a core dynamo from at least 4.2–3.56 Ga, mantle convection models of the Moon yield inadequate heat flux at the core-mantle boundary to sustain thermal core convection for such a long time. Past investigations of lunar dynamos have focused on a generally homogeneous, relatively dry Moon, while an initial compositionally stratified mantle is the expected consequence of a postaccretionary lunar magma ocean. Furthermore, recent re-examination of Apollo samples and geophysical data suggests that the Moon contains at least some regions with high water content. Using a finite element model, we investigate the possible consequences of a heterogeneously wet, compositionally stratified interior for the evolution of the Moon. We find that a postoverturn model of mantle cumulates could result in a core heat flux sufficiently high to sustain a dynamo through 2.5 Ga and a maximum surface, dipolar magnetic field strength of less than 1 μT for a 350-km core and near ∼2 μT for a 450-km core. We find that if water was transported or retained preferentially in the deep interior, it would have played a significant role in transporting heat out of the deep interior and reducing the lower mantle temperature. Thus, water, if enriched in the lower mantle, could have influenced core dynamo timing by over 1.0 Gyr and enhanced the vigor of a lunar core dynamo. Our results demonstrate the plausibility of a convective lunar core dynamo even beyond the period currently indicated by the Apollo samples.