Applications related to alkali-activated materials (AAMs) have received much attention due to their excellent mechanical properties and low-energy production. Although much research has focused on developing AAMs, their application is still limited. One of the primary reasons is the efflorescence. Not only does efflorescence affect the material aesthetics, but it also affects the mechanical performance, leading to a decrease in material quality. This paper first summarizes the current research on AAMs efflorescence. The formation process of efflorescence is divided into three parts: alkaline cation leaching, air carbonation, and efflorescence formation. Furthermore, the influences caused by different factors, including raw materials, curing conditions, AAMs modalities, etc., on the efflorescence are proposed. This paper highlights the solutions for efflorescence by avoiding free alkaline cation leaching and preventing air carbonation. The advantages and disadvantages of efflorescence are discussed in-depth, showing that it can be exploited under certain conditions, such as in wastewater treatment. This paper has important implications for the practical preparation and application of AAMs.

Low-carbon ecological cement composites are among the most promising construction materials. With low energy consumption, low carbon dioxide emissions, and high early strength, sulfoaluminate cement (SAC) is a low-carbon ecological building material. In addition, graphene nanoplates (GNPs) exhibit excellent performances. In this study, GNPs were dispersed by a combination of dispersant and ultrasonic treatment, and the dispersion effect of GNPs was characterized. The effect of GNPs on the hydration process and products of SAC was studied, revealing that GNPs accelerate SAC hydration. The hydration heat and ICP results showed that in the SAC hydrolysis stage, C₄A₃Š (ye’elimite) hydrolyzed and released Ca²⁺. GNPs absorbed the Ca²⁺, and the Ca²⁺ concentration around C₄A₃Š decreased, which would promote the hydrolysis of C₄A₃Š and release more Ca²⁺, accelerating the hydration of SAC and the nucleation effect of GNPs, and providing sites for the formation of hydration products. The analysis of XRD (X-Ray Diffraction) and TGA (Thermal Gravity Analysis) showed that GNPs promoted the hydration of SAC and formed more AFt (ettringite) and AH₃ (gibbsite). The generated hydration products fill the pores of the matrix and are closely connected to the GNPs to form a whole, which improves the cement matrix’s mechanical properties.

As a low-carbon ecological cement-based material, SAC (sulfoaluminate cement) has become a research hotspot. This study developed a SAC-based high-performance concrete material with good durability and high toughness. The mechanical properties of different scales of MSF (macro steel fiber) and mSF (micro steel fiber) reinforced sulfoaluminate cement-based composites were mainly studied, including their compressive strength, flexural strength, toughness index, and toughness ratio, and their resistance to sulfate erosion was characterized. The results show that adding MSF and HSF (hybrid steel fibers) can significantly improve concrete’s compressive and flexural strength compared with the Plain group. The compressive strength of SSF1 (1% MSF) and SSF2 (1.5% MSF) increased by 10.9%, 19.6%, and the compressive strength of HSF1 (0.1% mSF, 1.4% MSF), HSF2 (0.2% mSF, 1.3%MSF), HSF3 (0.3% mSF, 1.2% MSF), and HSF4 (0.5% mSF, 1.0% MSF) increased by 23.9%, 33.7%, 37.0%, 29.3%, respectively, while the flexural strength of HSF1, HSF2, HSF3, and HSF4 groups increased by 51.4%, 84.9%, 88.1%, and 64.2%. Compared with the single steel fiber (SSF) group, the HSF group has higher initial crack strength, equivalent flexural strength, toughness index, and toughness ratio. Hybrid fibers have a higher synergistic effect when mSF content is 0.2–0.3% and MSF content is 1.2–1.3%. The mechanism of multi-scale reinforcement of hybrid-steel-fiber-enhanced sulfoaluminate cement-based composites was researched. MSF bridges macro-cracks, mSF bridges micro-cracks, and these two different scales of steel fibers, through filling, bridging, anchoring, pulling off, and pulling out, improve the toughness of composite materials. The mechanism of sulfate corrosion resistance of sulfoaluminate cement-based composites was obtained. SO₄²⁻ entered the matrix and reacted and formed AFt, filling the matrix’s pores. The whole process is similar to the self-healing process of concrete.

Sulfoaluminate cement (SAC) is a low carbon ecological cement with good durability and is widely used in various projects. In addition, graphene nanoplates (GNPs) have excellent thermal, electrical, and mechanical properties and are excellent nano-filler. However, the hydration behavior of GNPs on SAC is still unclear. In this paper, the effect of GNPs on SAC hydration was investigated by isothermal calorimetry, and the hydration kinetic model and hydration kinetic equation of SAC was established, explaining the differences in cement hydration processes with and without GNPs on SAC based on a hydration kinetic model. Results indicate that the hydration exotherm of SAC mainly includes five stages: the initial stage, the induction stage, the acceleration stage, the deceleration stage, and the stable stage. The addition of GNPs promoted the hydration exotherm of SAC and accelerated the hydration reaction. Different from the hydration reaction of Portland cement, the hydration reaction of SAC is mainly a diffusion–reaction process.

In this paper, the effect of iron phase content on the calcination and properties of clinker and barium calcium sulfoaluminate cement was studied. The compressive strength of the samples was tested and combined with an XRD and SEM-EDS analysis, and the microstructure and composition of the barium calcium sulfoaluminate clinker and hydrated samples were characterized. The results showed that the oval-shaped particles were C₂S minerals, and the hexagonal plate-shaped or rhombohedral dodecahedral particles were C_2.75B_1.25A₃$\overline{\mathrm{S}}$. The Ba element was mainly distributed in the barium calcium sulfoaluminate region, and some of it was dissolved in C₂S; the Fe element was distributed between C_2.75B_1.25A₃$\overline{\mathrm{S}}$ and C₂S crystal grains in the form of an iron phase solid solution, which acted as a solvent. When the iron phase composition was C₄AF and the iron phase content was 5%, the early hydration and later strength were better, and the compressive strength after curing for 1, 3 and 28 days was 73.2 MPa, 97.9 MPa and 106.9 MPa, respectively. A proper amount of the iron phase can reduce the eutectic point of the sintered mature material system, increase the amount of liquid phase, reduce the viscosity of the liquid phase, effectively accelerate the migration of mineral ions and promote the formation and growth of minerals.

SAC (sulfoaluminate cement) has become a research hotspot as a low-carbon ecological cement. In addition, multi-walled carbon nanotubes have good thermal, mechanical, and electrical properties and can serve as excellent nano-reinforced cement-based fillers. This study explored the dispersion of carbon nanotubes (CNTs) and researched the effect of CNTs on the mechanical properties, hydration process, hydration products, and microstructure of SAC paste, and the mechanism of CNT-enhanced SAC paste was revealed. The results showed that the mechanical properties of SAC paste were significantly improved after the addition of CNTs. When the CNT content was 0.05%, 0.1%, and 0.15%, the compressive strength after 28 d was increased by 13.2%, 18.3%, and 22.5%, respectively; compared with the C0 group (without CNTs), the flexural strength increased by 8.2%, 11.3%, and 14.4%, respectively. The addition of CNTs accelerated the hydration process of SAC paste. Due to the adsorption effect and nucleation effect of CNTs, more hydration products were generated, filling the matrix’s pores and improving its compactness. The mechanism of CNTs enhanced SAC paste was revealed. CNTs and hydration products co-filled the pores, including AFt (ettringite) and AH₃ (gibbsite). CNTs improve the mechanical properties of SAC paste through filling, bridging, crack bending, deflection, pulling out, and pulling off.