Ceramic nanofibers (NFs) have recently been developed for advanced applications due to their unique properties. In this article, we review developments in electrospun ceramic NFs with regard to their fabrication process, properties, and applications. We find that surface activity of electrospun ceramic NFs is improved by post pyrolysis, hydrothermal, and carbothermal processes. Also, when combined with another surface modification methods, electrospun ceramic NFs result in the advancement of properties and widening of the application domains. With the decrease in diameter and length of a fiber, many properties of fibrous materials are modified; characteristics of such ceramic NFs are different from their wide and long (bulk) counterparts. In this article, electrospun ceramic NFs are reviewed with an emphasis on their applications as catalysts, membranes, sensors, biomaterials, fuel cells, batteries, supercapacitors, energy harvesting systems, electric and magnetic parts, conductive wires, and wearable electronic textiles. Furthermore, properties of ceramic nanofibers, which enable the above applications, and techniques to characterize them are briefly outlined.
8 December 2019 in Journal of Asian Ceramic Societies
This study investigates the effect of hydroxyapatite (HA) coating by plasma electrolytic oxidation (PEO) on the corrosion resistance of AZ31B Mg alloy. The effect of the HA concentration (5, 10 and 15 g.L−1) on the microstructure and corrosion behavior of coatings in the electrolyte was studied. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used to study the microstructure and composition. Polarization and electrochemical impedance spectroscopy (EIS) tests were applied to the bare and coated samples in simulated body fluid (SBF) to determine the resistance behavior and the kinetics of corrosion coatings. The results showed that HA could be distributed inside the coating along with MgO and Mg3 (PO4)2. Moreover, it was found that the porosity declined and the thickness of coatings increased with increases in the HA concentration. The results also indicated that the corrosion resistance of AZ31B Mg alloy was enhanced by coating with any amount of HA. The highest corrosion resistance was obtained with an electrolyte comprising 15 g.L−1 HA. The lowest corrosion current density (1.99 × 10−6 A.cm−2) was monitored in respect to the highest corrosion resistance.
1 April 2015 in Journal of Colloid and Interface Science