Increase in the spontaneous magnetization up to x < 0.5 is a sequence of appearance of the additional magnetic moment of 2 μ_B of the Ni²⁺ cations in tetrahedral positions. For x > 0.5, the moment decreases in octahedral positions and the spontaneous magnetization also decreases.

Intrinsic permeability of sendust alloys is determined from the measured microwave permittivity and permeability of composites filled with either spherical or flaky sendust powders. The permittivity and permeability measurements are performed applying the coaxial reflection-transmission technique in the 0.05 to 18 GHz frequency range. The effects of the filling factor, inclusion shape, and size on composite constitutive parameters are discussed. The permeability of metal inclusion is retrieved from the measured permeability of composites using a generalized Maxwell Garnett equation that accounts for the percolation threshold. The equation parameters are found by fitting the measured dependence of composite permittivity and permeability on frequency and filling. The inclusion dimensions calculated from the found parameters agree with the results of grain-size analyses. The alloy intrinsic permeability is retrieved from inclusion permeability with the account for skinning. The fitted frequency and damping factor of ferromagnetic resonance depend on the inclusion shape. The calculated reflectivity map of the flake-filled composite shows that sendust powders are promising fillers for interference suppressors and microwave absorbers at frequencies close to 1 GHz.

The use of a coaxial air-filled line as a test fixture for measuring complex permittivity and permeability often shows odd resonance-like behavior of material parameters as functions of frequency. This effect is typically either ascribed to the half-wavelength resonance at the sample length, or erroneously misinterpreted as intrinsic resonance behavior of the material. However, as is shown in this paper, such behavior can be attributed to excitation of the higher-order modes on the surface of the sample resulting in resonance absorption of electromagnetic energy in the test fixture. Herein, analytical, numerical, and experimental results show that there can actually be a significant impact of higher-order modes in a coaxial line on the extracted constitutive material parameters of samples.