In this article, hierarchical flower-like ZnO nanostructures with controlled morphology and dimensions have been synthesized by solution phase approach and functionalized by Au nanoparticles (AuNPs) with the combination of electrodeposition to explore novel applications. The photocatalytic activity and lithium storage capacity of these hybrid nanostructures have been investigated. It has been found that hybrid nanostructure combining the large specific surface area, stability and catalytic activity of small AuNPs, demonstrate the higher photocatalytic activity than that of pure ZnO. Furthermore, an initial discharge capacity of 1280 mA h g−1 and a reversible capacity over 392 mA h g−1 at the 50 cycles are achieved for the Au–ZnO hybrid nanostructure, which is found to be much better than that of any previously reported ZnO anodes. The improved lithium storage capacity and cycle life of the Au–ZnO electrode result from the Li activity of Au–ZnO phase. The photocatalytic and electrochemical activity of Au–ZnO hybrid nanostructures provide a new platform for energy storage, environmental remediation and photocatalysis applications.
This review has examined the advancements and challenges in the development of transition metal-based electrocatalysts for the alkaline water splitting reaction in the last decade.
A high-entropy O3-type layered oxide cathode Na(Fe 0.2 Co 0.2 Ni 0.2 Ti 0.2 Sn 0.1 Li 0.1 )O 2 with disordered distribution of multi-component transition metals suppresses the complex intermediate phase transition, enabling highly reversible electrochemical reaction.
7 October 2014 in Journal of Materials Chemistry A
Nitrogen-enriched porous carbon nanofiber networks (NPCNFs) were successfully prepared by using low-cost melamine and polyacrylonitrile as precursors via electrospinning followed by carbonization and NH3 treatments. The NPCNFs exhibited inter-connected nanofibrous morphology with a large specific surface area, well-developed microporous structure, relatively high-level nitrogen doping and great amount of pyridinic nitrogen. As free-standing new anode materials in lithium-ion batteries (LIBs), the NPCNFs showed ultrahigh capacity, good cycle performance and superior rate capability with a reversible capacity of as high as 1323 mA h g−1 at a current density of 50 mA g−1. These attractive characteristics make the NPCNFs materials very promising anode candidates for high-performance LIBs and, as free-standing electrode materials to be used in other energy conversion and storage devices.