Furfurylation with a low concentration of furfuryl alcohol (FA) promotes the improvement of the properties and the effectiveness of FA on cell–wall action without darkening the furfurylated wood to the point that it affects its applications. In this paper, the effects of furfurylation on the hygroscopicity and water uptake dimensional stability of poplar (Populus sp.) and Chinese fir (Cunninghamia lanceolata) were analyzed. Meanwhile, the distribution of FA resin, the relationship between wood and water, the change in pore size distribution, and the weight percentage gain and cell wall bulking coefficient of wood were also investigated. The results were as follows: (1) A low concentration of FA could better enter the cell walls of the Chinese fir than the poplar, as FA resin was almost cured in the secondary walls, cell corners, and compound middle lamellae when a 10% concentration of FA was applied to the Chinese fir and poplar. When the FA concentration was increased to 30%, there were no significant increases in the amount of FA entering the cell walls and the amounts of FA cured in the cell lumen of the poplar were greater than those of the Chinese fir. Meanwhile, the modification of cell walls was more suitable in poplar than in Chinese fir. (2) The pointed ends of the pit chambers and the pit apertures (800–1000 nm) in the poplar and the small pores of the pit membranes and the pit apertures (1–6 μm) in the Chinese fir were partially deposited by the FA resin, which formed new pores in the size ranges of 80–600 nm and 15–100 nm, respectively. The porosity of the poplar was greater than that of the Chinese fir, and the bulk density of the poplar was less than that of the Chinese fir before and after modification. (3) Furfurylation with a low concentration of FA was able to better reduce the equilibrium moisture content, improve the anti-swelling efficiency, and enhance the dimensional stability of the poplar wood compared to the Chinese fir. Furfurylation effectively reduced water uptake due to the hydrophobic property of the FA resin. The water uptake of the Chinese fir increased by 17%–19% in second cyclic water soaking when treated with FA with various concentrations, which indicated the loss and leaching of FA resin during the test. Low-field NMR was used to demonstrate that the furfurylation not only reduced the amount of water but also affected the combination state of bound and free water with wood. Thus, furfurylation at a low concentration is a feasible method by which to extend applications of furfurylated wood.
Furfurylation can effectively improve the quality of fast-growing wood, but its leachability is unclear. In this study, fast-growing poplar (Populus sp.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.) were impregnated with low concentrations of 5%–20% furfuryl alcohol (FA), and the chemical and microscopic changes during leaching tests were analyzed by UV spectra and confocal laser scanning microscopy (CLSM). The results show that FA impregnation can regulate the weight percentage gain, but its effectiveness in regulating the cell wall bulking coefficient decreased as the impregnation concentration was increased. Impregnation with 15% and 20% FA showed no significant difference in the effect on volume swelling efficiency. The inverse relationship between the concentration of FA and the leaching rate was demonstrated by leaching tests, UV spectra, and CLSM. Notably, the leaching rate of poplar and Chinese fir wood was more than 30% when impregnated with 5% FA. Although the entirety of the furfuryl alcohol was deposited in the cell wall when impregnated with low concentrations of FA, the binding was not stable. The weight percentage gain of furfurylated Chinese fir was greater than that of poplar, but its leaching rate was lower, indicating that the cured furfuryl alcohol resin in poplar was not as stable as that in Chinese fir. Therefore, differences in tree species should be considered in low-concentration FA impregnation, as the improvement effect of concentrations below 10% on the properties of fast-growing wood is weak and the leaching rate of FA is significant.
Yunnan Dendrocalamus sinicus Chia et J. L. Sun (YDS) is a giant bamboo species with a diameter at breast height of up to nearly 40 cm. It is endemic to Yunnan, China, and only a very small portion of it is directly used as load-bearing beams and columns in the dwellings of ethnic minorities, such as in Dai architecture. Due to the structural characteristics of its hollow and thin walls, systematic physical and mechanical property testing of this species faces significant challenges in terms of methods and means. This issue has become one of the main barriers to the realization of its large-scale industrial use. Therefore, this paper systematically tests and studies YDS’s three kinds of strength (tension, compression, and shear), modulus of elasticity, and six Poisson’s ratios with the help of digital image correlation (DIC) technology and self-created material testing methods. The (1) tensile, compressive, and shear strengths and moduli in longitudinal, radial, and chordal directions; (2) tensile strengths and moduli of bamboo green, flesh, and yellow layers in the thickness direction of the bamboo wall; and (3) six Poisson’s ratios under tensile and compressive stresses were obtained for YDS. It was also found that the tensile strength (378.8 MPa) of the green layer of YDS exceeded the yield strength (355 MPa) of 45# steel, making it a potential high-strength engineering material or fiber-reinforced material.
In order to investigate the mechanism of the effect of asymmetric reinforcement on the static-bending properties of wood, this paper tests and analyzes the static-bending properties of SPF wood and seven different types of asymmetric fiber surface-reinforced wood (AFRWC) formed by SPF wood as the substrate and bamboo and carbon fibers as the reinforcement materials. The results of the study found that (1) the moduli of rupture of the seven types of AFRWC were increased to varying degrees, but the static-bending moduli of elasticity increased or decreased; (2) the asymmetric reinforcement changed the cross-section strain distribution and damage type of the wood in static bending; (3) the results of the cross-section strain-field tests and the ABAQUS finite element simulation showed that the asymmetric reinforcement method of bonding the bamboo material and the two layers of CFRP in the compression and tensile zones, respectively, can greatly enhance the static-bending performance of the wood. The error between the simulated and measured values of specimens MOR and MOE is only −0.7% and −7.3%, respectively. This type of asymmetric reinforcement makes it possible to obtain a more reasonable cross-section stress distribution.
This study investigated the effects of adhesive resination and bamboo strand content on the physical and mechanical properties of thick Bamboo-Wood-oriented strand board (BWOSB), such as the air dry density (ADD), internal bond strength (IB), water absorption thickness swelling (TS), modulus of rupture (MOR), modulus of elasticity (MOE), and gluing properties. The raw materials used included large strands prepared from Chinese fir (Cunninghamia lanceolata), bamboo (Phyllostachys edulis), and modified isocyanate resin (PMDI). In this study, BWOSB specimens with different adhesive resination and bamboo strand content were fabricated, and their physical–mechanical properties were examined. It was found that the physical and mechanical properties of BWOSB with 8% PMDI resination were better than those with 5%, and their gluing damage was mostly in the form of the tearing of the raised vascular bundles of bamboo strands and the wood-breaking damage of wood strands. With the increase in the proportion of bamboo strands, the internal bonding strength and the short-span shear strength of BWOSB showed a tendency to decrease at first and then increase. The swelling rate of the water absorption thickness showed a tendency to decrease, and the other properties of BWOSB did not show a clear correlation with the change in the proportion of bamboo strands. The unique gluing interface between the bamboo and wood strands, which either used the “keyway” type of gluing effect or the “nail” type of gluing effect, determined the gluing performance of BWOSB, and the proportion of bamboo and wood strands influenced the gluing interface and gluing type of BWOSB, which ultimately affected the gluing performance of BWOSBs. The proportion of bamboo and wood strands also affected the gluing properties of BWOSBs by influencing the gluing interface and gluing type. This study provides a reference for the development of the production process of thick BWOSB and its application in the field of heavy load construction.
To study the static bending creep properties of glass fiber reinforced wood, glass fiber reinforced poplar (GFRP) specimens were obtained by pasting glass fiber on the upper and lower surfaces of Poplar (Populus euramevicana, P), the performance of Normal Creep (NC) and Mechanical Sorptive Creep (MSC) of GFRP and their influencing factors were tested and analyzed. The test results and analysis show that: (1) The MOE and MOR of Poplar were increased by 17.06% and 10.00% respectively by the glass fiber surface reinforced composite. (2) The surface reinforced P with glass fiber cloth only exhibits the NC pattern of wood and loses the MSC characteristics of wood, regardless of the constant or alternating changes in relative humidity. (3) The instantaneous elastic deformation, viscoelastic deformation, viscous deformation and total creep deflection of GFRP are positively correlated with the stress level of the external load applied to the specimen. Still, the specimen’s creep recovery rate is negatively correlated with the stress level of the external load applied to the specimen. The static creep deflection and viscous deformation of GFRP increase with the increase of the relative humidity of the environment. (4) The MSC maximum creep deflection of GFRP increased by only 7.41% over the NC maximum creep deflection, but the MSC maximum creep deflection of P increased by 199.25% over the NC maximum creep deflection. (5) The Burgers 4-factor model and the Weibull distribution equation can fit the NC and NC recovery processes of GFRP well.