As supplementary cementitious material, glass powder has been widely used in concrete, and many investigations on the mechanical properties of glass powder concrete have been carried out. However, there is a lack of investigations on the binary hydration kinetics model of glass powder-cement. Based on the pozzolanic reaction mechanism of glass powder, the purpose of this paper is to establish a theoretical model of the binary hydraulic kinetics model of glass powder-cement to investigate the effect of glass powder on cement hydration. The hydration process of glass powder-cement mixed cementitious materials with different glass powder contents (e.g., 0, 20%, 50%) was simulated using the finite element method (FEM). The numerical simulation results are in good agreement with the experimental data of hydration heat in the literature, which verifies the reliability of the proposed model. The results show that the glass powder can dilute and accelerate the hydration of cement. Compared to the sample with 5% glass powder content, the hydration degree of the glass powder decreased by 42.3% for the sample with 50% glass powder content. More importantly, the reactivity of the glass powder decreases exponentially with the increase in the glass particle size. In addition, the reactivity of the glass powder tends to be stable when the glass particle size is greater than 90 μm. With the increase in the replacement rate of the glass powder, the reactivity of the glass powder decreases. When the replacement rate of the glass powder is greater than 45%, the concentration of CH reaches a peak at the early stage of the reaction. The research in this paper reveals the hydration mechanism of glass powder and provides a theoretical basis for the application of glass powder in concrete.

The composite micronized powder is prepared by using blast furnace slag (BFS), water-quenched manganese slag (WQMS), manganese tailing slag (MTS) and desulfurization gypsum (DG) and grinding aid (GA) through orthogonal test optimization design. The effect of the doping amount of each solid waste on the fluidity, activity at different ages and resistance to chloride ion penetration of the composite micropowder was studied systematically, and the exothermic characteristics of hydration of the composite micropowder with the optimal ratio were tested. The results showed that the amount of MTS dosing was the most significant factor among the four factors on the activity index of composite micronized powder at 7 d and 28 d. The activity index at 28 d decreased and then increased with the increase in MTS dosing; the amount of BFS dosing was the most significant factor affecting the fluidity and chloride ion permeation resistance of composite micronized powder. With an increase in BFS dosing, the fluidity ratio of composite micronized powder increased and then decreased; the electric flux of the matrix decreased, and the chloride ion permeation resistance increased. The optimal ratio of composite powder with the highest 28 d activity is 35% BFS, 30% MTS, 0.3% GA, 5% DG and 30% WQMS. The hydration rate and cumulative heat release of the slurry prepared with the optimal ratio of composite micronized powder to cement (1:1) are lower than those of pure cement slurry. The microstructure of the mortar test block prepared with a 1:1 composite of cement is more compact than that of the pure cement mortar test block, and the pores are fewer.